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Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds: XXXVII. 1 Effect of Nucleofuge and Solvent of the Relative Rates of Heterolysis of 1Halo1-methylcyclopentanes and 1Halo1-methylcyclohexanes. Correlation Analysis of Solvation Effects

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dc.contributor.author Dvorko, G en
dc.contributor.author Koshchii, I en
dc.contributor.author Ponomareva, E en
dc.date.accessioned 2014-03-01T01:19:05Z
dc.date.available 2014-03-01T01:19:05Z
dc.date.issued 2003 en
dc.identifier.uri http://hdl.handle.net/123456789/15372
dc.subject Correlation Analysis en
dc.subject Kinetics en
dc.subject Relative Rate en
dc.title Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds: XXXVII. 1 Effect of Nucleofuge and Solvent of the Relative Rates of Heterolysis of 1Halo1-methylcyclopentanes and 1Halo1-methylcyclohexanes. Correlation Analysis of Solvation Effects en
heal.type journalArticle en
heal.identifier.primary 10.1023/B:RUGC.0000015993.04565.ee en
heal.identifier.secondary http://dx.doi.org/10.1023/B:RUGC.0000015993.04565.ee en
heal.publicationDate 2003 en
heal.abstract The effect of solvent ionizing ability on heterolysis rate enhances in the series 1-chloro-1-methylcyclohexane < 1-bromo-1-methylcyclohexane ˜ 1-chloro-1-methylcyclopentane < 1-bromo-1-methyl- cyclopentane. The lower sensitivity of cyclohexyl substrates compared with cyclopentyl is determined by conformational effects. Bromides are more sensitive to solvent effects than chlorides because of the stronger polarizability of the C-Br bond. en
heal.journalName Russian Journal of General Chemistry en
dc.identifier.doi 10.1023/B:RUGC.0000015993.04565.ee en


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