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Photo-assisted oxidation of an oily wastewater using hydrogen peroxide

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dc.contributor.author Philippopoulos, CJ en
dc.contributor.author Poulopoulos, SG en
dc.date.accessioned 2014-03-01T01:19:25Z
dc.date.available 2014-03-01T01:19:25Z
dc.date.issued 2003 en
dc.identifier.issn 0304-3894 en
dc.identifier.uri http://hdl.handle.net/123456789/15482
dc.subject H2O2 en
dc.subject Hydroxyl radical en
dc.subject Photo-Fenton en
dc.subject Photo-oxidation en
dc.subject Ultraviolet treatment en
dc.subject.classification Engineering, Environmental en
dc.subject.classification Engineering, Civil en
dc.subject.classification Environmental Sciences en
dc.subject.other Chemical oxygen demand en
dc.subject.other Hydrogen peroxide en
dc.subject.other Oils and fats en
dc.subject.other Oxidation en
dc.subject.other pH effects en
dc.subject.other Photochemical reactions en
dc.subject.other Oily wastewater en
dc.subject.other Wastewater treatment en
dc.subject.other carboxylic acid en
dc.subject.other ethylene glycol en
dc.subject.other ferric ion en
dc.subject.other hydrogen peroxide en
dc.subject.other lubricating agent en
dc.subject.other water en
dc.subject.other oil en
dc.subject.other photochemical treatment en
dc.subject.other wastewater en
dc.subject.other water treatment en
dc.subject.other article en
dc.subject.other chemical oxygen demand en
dc.subject.other gas chromatography en
dc.subject.other mass spectrometry en
dc.subject.other pH en
dc.subject.other photooxidation en
dc.subject.other purification en
dc.subject.other ultraviolet irradiation en
dc.subject.other waste water en
dc.subject.other Hydrogen Peroxide en
dc.subject.other Industrial Waste en
dc.subject.other Water Pollutants, Chemical en
dc.subject.other Water Purification en
dc.subject.other Gadus morhua en
dc.title Photo-assisted oxidation of an oily wastewater using hydrogen peroxide en
heal.type journalArticle en
heal.identifier.primary 10.1016/S0304-3894(02)00357-6 en
heal.identifier.secondary http://dx.doi.org/10.1016/S0304-3894(02)00357-6 en
heal.language English en
heal.publicationDate 2003 en
heal.abstract The primary objective was to study the purification of an oily wastewater from a lubricant production unit using ultraviolet irradiation and hydrogen peroxide. The influence of hydrogen peroxide concentration, initial pH of the solution and of the addition of ferric ions on the chemical oxygen demand (COD) was examined. In each case, the concentration of the compounds contained in the oily wastewater was determined. It was shown that a 20-45% COD removal was achieved with 830-1660 mg 1(-1) H2O2. Gas chromatography-mass spectrometry analysis showed that the organic compounds of the wastewater decomposed to organic acids that were very resistant to photo-oxidation. Among these compounds, ethylene glycol remained almost unchanged by the attack from hydroxyl radicals. Acidic pH and Fe(III) addition enhanced significantly the photo-oxidation of the wastewater. (C) 2003 Elsevier Science B.V. All rights reserved. en
heal.publisher ELSEVIER SCIENCE BV en
heal.journalName Journal of Hazardous Materials en
dc.identifier.doi 10.1016/S0304-3894(02)00357-6 en
dc.identifier.isi ISI:000181804600015 en
dc.identifier.volume 98 en
dc.identifier.issue 1-3 en
dc.identifier.spage 201 en
dc.identifier.epage 210 en


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