Kinetic studies of homogeneous nitration of toluene

Papayannakos, NG; Petrolekas, P

dc.contributor.author	Papayannakos, NG	en
dc.contributor.author	Petrolekas, P	en
dc.date.accessioned	2014-03-01T01:08:54Z
dc.date.available	2014-03-01T01:08:54Z
dc.date.issued	1992	en
dc.identifier.issn	0888-5885	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/10726
dc.subject	Kinetics	en
dc.subject.classification	Engineering, Chemical	en
dc.subject.other	Acids - Mixtures	en
dc.subject.other	Chemical Reactions - Reaction Kinetics	en
dc.subject.other	Chemical Reactions - Thermal Effects	en
dc.subject.other	Nitric Acid - Applications	en
dc.subject.other	Sulfuric Acid - Applications	en
dc.subject.other	Acid Composition	en
dc.subject.other	Activation Energy	en
dc.subject.other	Toluene	en
dc.title	Kinetic studies of homogeneous nitration of toluene	en
heal.type	journalArticle	en
heal.identifier.primary	10.1021/ie00006a006	en
heal.identifier.secondary	http://dx.doi.org/10.1021/ie00006a006	en
heal.language	English	en
heal.publicationDate	1992	en
heal.abstract	The dependence of the nitration rates of toluene in an aqueous phase on reaction temperature and mixed acid composition has been examined. Ternary solutions HNO3-H2SO4-H2O with compositions normally employed in industrial applications have been used as the nitration medium. The activation energy was found to increase with an increase in either the HNO3 content of the nitration medium at constant water content or the H2O content at constant HNO3 content. A kinetic equation is proposed which is applicable over the whole range of conditions used. © 1992 American Chemical Society.	en
heal.publisher	AMER CHEMICAL SOC	en
heal.journalName	Industrial & Engineering Chemistry Research	en
dc.identifier.doi	10.1021/ie00006a006	en
dc.identifier.isi	ISI:A1992HZ06400006	en
dc.identifier.volume	31	en
dc.identifier.issue	6	en
dc.identifier.spage	1457	en
dc.identifier.epage	1461	en