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The mere concept of an ideal gas

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dc.contributor.author Masavetas, KA en
dc.date.accessioned 2014-03-01T01:07:41Z
dc.date.available 2014-03-01T01:07:41Z
dc.date.issued 1989 en
dc.identifier.issn 0895-7177 en
dc.identifier.uri https://dspace.lib.ntua.gr/xmlui/handle/123456789/10122
dc.relation.uri http://www.scopus.com/inward/record.url?eid=2-s2.0-0024930549&partnerID=40&md5=44bd744539e608ed7be6607ce4094353 en
dc.subject.classification Computer Science, Interdisciplinary Applications en
dc.subject.classification Computer Science, Software Engineering en
dc.subject.classification Mathematics, Applied en
dc.subject.other Equations of State en
dc.subject.other Mathematical Techniques - Applications en
dc.subject.other Thermodynamic Properties en
dc.subject.other Definitions en
dc.subject.other Ideal Gas en
dc.subject.other Gases, Inert en
dc.title The mere concept of an ideal gas en
heal.type journalArticle en
heal.language English en
heal.publicationDate 1989 en
heal.abstract There exists a tradition to define an ideal gas as one described by the equation of state pV = nRT. The inconsiderate application of this ""definition"" meets with serious reservations because it may lead to a host of conceptual inconsistencies. In this paper the view is expounded that the problem of the rigorous definition of the ideal gas presupposes the accurate determination of the scientific region in which it will be applied and requires the existence of an organized formalism for the mathematical foundation of Thermodynamics in whose ""language"" it will be laid down. From the attempted analysis it is ascertained that instead of speaking of the ideal gas, in reality we should refer, according to the case, to a different class of ideal gases. For each of them alternative definitions are laid down and the equivalence between them, as well as their difference from the respective alternative definitions of another class of ideal gases, is proved. In conclusion, from the whole investigation it comes out that, as a rule, the traditional ""definition"" is simply and solely a necessary, but not sufficient, criterion to define the ""ideal gas"". Depending on the part of Physical Chemistry to which we refer, it is necessary to complement the traditional definition of the ideal gas with other, additional, proper axioms, which are different for each case. Various definitions of the ideal gas are analysed, and changes are proposed. © 1989. en
heal.publisher PERGAMON-ELSEVIER SCIENCE LTD en
heal.journalName Mathematical and Computer Modelling en
dc.identifier.isi ISI:A1989U707700005 en
dc.identifier.volume 12 en
dc.identifier.issue 6 en
dc.identifier.spage 651 en
dc.identifier.epage 657 en


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