Plasticized PVC films/petroleum oils: The effect of ultraviolet irradiation on plasticizer migration

Duvis, T; Karles, G; Papaspyrides, CD

dc.contributor.author	Duvis, T	en
dc.contributor.author	Karles, G	en
dc.contributor.author	Papaspyrides, CD	en
dc.date.accessioned	2014-03-01T01:08:29Z
dc.date.available	2014-03-01T01:08:29Z
dc.date.issued	1991	en
dc.identifier.issn	0021-8995	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/10525
dc.subject	Ultraviolet	en
dc.subject.classification	Polymer Science	en
dc.subject.other	Petroleum Products	en
dc.subject.other	Plasticizers - Diffusion	en
dc.subject.other	Plastics Films - Radiation Effects	en
dc.subject.other	Ultraviolet Radiation - Effects	en
dc.subject.other	Migration Kinetics	en
dc.subject.other	Plasticized Polyvinyl Chlorides	en
dc.subject.other	Plasticizer Migration	en
dc.subject.other	Polyvinyl Chlorides	en
dc.title	Plasticized PVC films/petroleum oils: The effect of ultraviolet irradiation on plasticizer migration	en
heal.type	journalArticle	en
heal.identifier.primary	10.1002/app.1991.070420123	en
heal.identifier.secondary	http://dx.doi.org/10.1002/app.1991.070420123	en
heal.language	English	en
heal.publicationDate	1991	en
heal.abstract	Plasticizer migration from flexible poly(vinyl chloride) comprises an important aspect, especially when packaging foodstuffs and pharamaceuticals. Much of the published work has been intended either to correlate migration into simulants with that into foods or to study migration into simpler extractants, enabling the various parameters involved in migration to be studied in isolation. According to the latter approach, the migration of dioctyl phthalate into petroleum oils has been studied already in our laboratory and in this paper results are presented in an attempt to reduce or prevent migration by u.v. irradiation. The effect of irradiation time on short- and long-term migration behavior was examined together with the influence of the immersion temperature. The nature of the liquid environment seemed to be a predominant aspect: high viscosity oils presented a satisfactory behavior in contrast with those of lower viscosity in which the prevention effect was rather negligible. On the other hand, primary kinetics studies yielded similar results with those already established for untreated material (i.e., good conformity to the short time Fickian approximation).	en
heal.publisher	JOHN WILEY & SONS INC	en
heal.journalName	Journal of Applied Polymer Science	en
dc.identifier.doi	10.1002/app.1991.070420123	en
dc.identifier.isi	ISI:A1991EN42200022	en
dc.identifier.volume	42	en
dc.identifier.issue	1	en
dc.identifier.spage	191	en
dc.identifier.epage	198	en