A comparison of different strategies for lipase-catalyzed synthesis of partial glycerides

Bornscheuer, U; Stamatis, H; Xenakis, A; Yamane, T; Kolisis, FN

dc.contributor.author	Bornscheuer, U	en
dc.contributor.author	Stamatis, H	en
dc.contributor.author	Xenakis, A	en
dc.contributor.author	Yamane, T	en
dc.contributor.author	Kolisis, FN	en
dc.date.accessioned	2014-03-01T01:09:39Z
dc.date.available	2014-03-01T01:09:39Z
dc.date.issued	1994	en
dc.identifier.issn	0141-5492	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/11121
dc.subject.classification	Biotechnology & Applied Microbiology	en
dc.subject.other	acylglycerol	en
dc.subject.other	glycerol	en
dc.subject.other	lauric acid	en
dc.subject.other	monoacylglycerol	en
dc.subject.other	solvent	en
dc.subject.other	triacylglycerol lipase	en
dc.subject.other	vinyl derivative	en
dc.subject.other	article	en
dc.subject.other	burkholderia cepacia	en
dc.subject.other	esterification	en
dc.subject.other	intermethod comparison	en
dc.subject.other	nonhuman	en
dc.subject.other	synthesis	en
dc.subject.other	Burkholderia	en
dc.subject.other	Burkholderia cepacia	en
dc.subject.other	Pseudomonas	en
dc.title	A comparison of different strategies for lipase-catalyzed synthesis of partial glycerides	en
heal.type	journalArticle	en
heal.identifier.primary	10.1007/BF00136474	en
heal.identifier.secondary	http://dx.doi.org/10.1007/BF00136474	en
heal.language	English	en
heal.publicationDate	1994	en
heal.abstract	Four different approaches for the synthesis of monolaurylglycerol (MLG) by non specific Pseudomonas cepacia lipase in a crude and purified form have been studied: a. The direct esterification of glycerol by lauric acid in bis-(2-ethylhexyl)sulfosuccinate sodium salt (AOT)/isooctane microemulsion systems; b. the transesterification of glycerol by vinyl laurate in the presence or not of any solvent; c. solid-phase glycerolysis of trilaurin; and, d. transesterification of protected glycerol, 1,2-O-isopropylidene glycerol, by vinyl laurate, in the presence or not of any solvent. It was found that in the two latter cases (d and c) the formation of pure MLG was occurred, while in the first two cases (a and b) apart of MLG the formation of DLG was also observed.	en
heal.publisher	CHAPMAN HALL LTD	en
heal.journalName	Biotechnology Letters	en
dc.identifier.doi	10.1007/BF00136474	en
dc.identifier.isi	ISI:A1994NZ82800008	en
dc.identifier.volume	16	en
dc.identifier.issue	7	en
dc.identifier.spage	697	en
dc.identifier.epage	702	en