dc.contributor.author |
PAPADOPOULOS, K |
en |
dc.contributor.author |
NIKOKAVOURAS, J |
en |
dc.contributor.author |
DIMOTIKALI, D |
en |
dc.date.accessioned |
2014-03-01T01:10:11Z |
|
dc.date.available |
2014-03-01T01:10:11Z |
|
dc.date.issued |
1994 |
en |
dc.identifier.issn |
0941-1216 |
en |
dc.identifier.uri |
https://dspace.lib.ntua.gr/xmlui/handle/123456789/11333 |
|
dc.subject.classification |
Chemistry, Applied |
en |
dc.subject.classification |
Chemistry, Multidisciplinary |
en |
dc.subject.other |
REDOX SYSTEMS |
en |
dc.subject.other |
CHEMILUMINESCENCE |
en |
dc.subject.other |
NUCLEOPHILES |
en |
dc.subject.other |
MECHANISM |
en |
dc.title |
REACTIONS OF LUCIGENIN IN PROTIC SOLVENTS IN THE PRESENCE OF AMINES |
en |
heal.type |
journalArticle |
en |
heal.identifier.primary |
10.1002/prac.19943360605 |
en |
heal.identifier.secondary |
http://dx.doi.org/10.1002/prac.19943360605 |
en |
heal.language |
English |
en |
heal.publicationDate |
1994 |
en |
heal.abstract |
Lucigenin (NN'-dimethyl-9,9'-biacridinium nitrate) 1 on heating under reflux in protic solvents in the presence of amines gives rise to the NN'-dimethyl-9,9'-biacridylidene 2 (DBA) or protected hemiaminal N-methoxymethyl-9,9'-biacridylidene 3. On the other hand acid hydrolysis and synchronous oxidation of hemiaminal 3 followed by reaction of monomethyl-biacridinium nitrate 4 with sodium hydroxide in methanol or water leads to biacridine 5 (overall yield ca. 33%). |
en |
heal.publisher |
JOHANN AMBROSIUS BARTH VERLAG |
en |
heal.journalName |
JOURNAL FUR PRAKTISCHE CHEMIE-CHEMIKER-ZEITUNG |
en |
dc.identifier.doi |
10.1002/prac.19943360605 |
en |
dc.identifier.isi |
ISI:A1994PD05300004 |
en |
dc.identifier.volume |
336 |
en |
dc.identifier.issue |
6 |
en |
dc.identifier.spage |
506 |
en |
dc.identifier.epage |
508 |
en |