REACTIONS OF LUCIGENIN IN PROTIC SOLVENTS IN THE PRESENCE OF AMINES

PAPADOPOULOS, K; NIKOKAVOURAS, J; DIMOTIKALI, D

dc.contributor.author	PAPADOPOULOS, K	en
dc.contributor.author	NIKOKAVOURAS, J	en
dc.contributor.author	DIMOTIKALI, D	en
dc.date.accessioned	2014-03-01T01:10:11Z
dc.date.available	2014-03-01T01:10:11Z
dc.date.issued	1994	en
dc.identifier.issn	0941-1216	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/11333
dc.subject.classification	Chemistry, Applied	en
dc.subject.classification	Chemistry, Multidisciplinary	en
dc.subject.other	REDOX SYSTEMS	en
dc.subject.other	CHEMILUMINESCENCE	en
dc.subject.other	NUCLEOPHILES	en
dc.subject.other	MECHANISM	en
dc.title	REACTIONS OF LUCIGENIN IN PROTIC SOLVENTS IN THE PRESENCE OF AMINES	en
heal.type	journalArticle	en
heal.identifier.primary	10.1002/prac.19943360605	en
heal.identifier.secondary	http://dx.doi.org/10.1002/prac.19943360605	en
heal.language	English	en
heal.publicationDate	1994	en
heal.abstract	Lucigenin (NN'-dimethyl-9,9'-biacridinium nitrate) 1 on heating under reflux in protic solvents in the presence of amines gives rise to the NN'-dimethyl-9,9'-biacridylidene 2 (DBA) or protected hemiaminal N-methoxymethyl-9,9'-biacridylidene 3. On the other hand acid hydrolysis and synchronous oxidation of hemiaminal 3 followed by reaction of monomethyl-biacridinium nitrate 4 with sodium hydroxide in methanol or water leads to biacridine 5 (overall yield ca. 33%).	en
heal.publisher	JOHANN AMBROSIUS BARTH VERLAG	en
heal.journalName	JOURNAL FUR PRAKTISCHE CHEMIE-CHEMIKER-ZEITUNG	en
dc.identifier.doi	10.1002/prac.19943360605	en
dc.identifier.isi	ISI:A1994PD05300004	en
dc.identifier.volume	336	en
dc.identifier.issue	6	en
dc.identifier.spage	506	en
dc.identifier.epage	508	en