Synthesis, NMR spectroscopic and X-ray crystallographic studies of N-acetyl-3-butanoyltetramic acid

Barkley, JV; Markopoulos, J; Markopoulou, O

dc.contributor.author	Barkley, JV	en
dc.contributor.author	Markopoulos, J	en
dc.contributor.author	Markopoulou, O	en
dc.date.accessioned	2014-03-01T01:10:18Z
dc.date.available	2014-03-01T01:10:18Z
dc.date.issued	1994	en
dc.identifier.issn	0300-9580	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/11363
dc.relation.uri	http://www.scopus.com/inward/record.url?eid=2-s2.0-37049070763&partnerID=40&md5=692d2b2cdcb6396e3bb58e5a3682b811	en
dc.subject.classification	Chemistry, Organic	en
dc.subject.classification	Chemistry, Physical	en
dc.subject.other	SUBSTITUTED TETRAMIC ACIDS	en
dc.subject.other	ACTIVE METHYLENE-COMPOUNDS	en
dc.subject.other	3-ACYLTETRAMIC ACIDS	en
dc.subject.other	ACYLAMINOACETYL DERIVATIVES	en
dc.subject.other	CYCLIZATION	en
dc.subject.other	PYRROLIDINE-2,4-DIONES	en
dc.subject.other	(+)-IKARUGAMYCIN	en
dc.subject.other	IKARUGAMYCIN	en
dc.subject.other	METABOLITE	en
dc.subject.other	COMPLEXES	en
dc.title	Synthesis, NMR spectroscopic and X-ray crystallographic studies of N-acetyl-3-butanoyltetramic acid	en
heal.type	journalArticle	en
heal.language	English	en
heal.publicationDate	1994	en
heal.abstract	The reaction of N-acetylglycine p-nitrophenyl ester with the anion of an active methylene compound proceeds to give N-acetyl-3-butanoyltetramic acid. The influence of the N-acetyl group on the equilibrium between different 'internal' and 'external' tautomeric forms of N-acetyl-3-butanoyltetramic acid was investigated by H-1 and C-13 NMR spectroscopy. The structure of this compound was confirmed by an X-ray crystal structure determination.	en
heal.publisher	ROYAL SOC CHEMISTRY	en
heal.journalName	Journal of the Chemical Society, Perkin Transactions 2	en
dc.identifier.isi	ISI:A1994NQ34100024	en
dc.identifier.issue	6	en
dc.identifier.spage	1271	en
dc.identifier.epage	1274	en