Microemulsions as a tool for the regioselective lipase-catalysed esterification of aliphatic diols

Macris, JB; Stamatis, H; Kolisis, FN

dc.contributor.author	Macris, JB	en
dc.contributor.author	Stamatis, H	en
dc.contributor.author	Kolisis, FN	en
dc.date.accessioned	2014-03-01T01:12:04Z
dc.date.available	2014-03-01T01:12:04Z
dc.date.issued	1996	en
dc.identifier.issn	0175-7598	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/11941
dc.subject	Reaction Rate	en
dc.subject	Oleic Acid	en
dc.subject	Product Distribution	en
dc.subject.classification	Biotechnology & Applied Microbiology	en
dc.subject.other	1,3 butanediol	en
dc.subject.other	oleic acid	en
dc.subject.other	triacylglycerol lipase	en
dc.subject.other	water oil cream	en
dc.subject.other	article	en
dc.subject.other	biotechnology	en
dc.subject.other	candida	en
dc.subject.other	controlled study	en
dc.subject.other	enzyme activity	en
dc.subject.other	enzyme specificity	en
dc.subject.other	esterification	en
dc.title	Microemulsions as a tool for the regioselective lipase-catalysed esterification of aliphatic diols	en
heal.type	journalArticle	en
heal.identifier.primary	10.1007/s002530050854	en
heal.identifier.secondary	http://dx.doi.org/10.1007/s002530050854	en
heal.language	English	en
heal.publicationDate	1996	en
heal.abstract	The efficiency of Humicola lanuginosa and Candida cylindracea lipases to catalyse the regioselective esterification of butane-1,3-diol with oleic acid has been demonstrated in water-in-oil microemulsion systems stabilized with sodium (bis-2-ethylhexyl) sulphosuccinate as a surfactant in isooctane. Mono- and diesters were selectively synthesized with high reaction rates. The product distribution depends on the positional specificity of the lipases. Water-in-oil microemulsions appear to be an effective and fast system for the regioselective enzymatic esterification of diols.	en
heal.publisher	SPRINGER VERLAG	en
heal.journalName	Applied Microbiology and Biotechnology	en
dc.identifier.doi	10.1007/s002530050854	en
dc.identifier.isi	ISI:A1996WH39900011	en
dc.identifier.volume	46	en
dc.identifier.issue	5-6	en
dc.identifier.spage	521	en
dc.identifier.epage	523	en