A differential method for the analysis of chemical kinetics results based on reversed-flow gas chromatography

Roubani-Kalantzopoulou, F; Kalogirou, E; Kalantzopoulos, A; Metaxa, H; Thede, R; Katsanos, NA; Sotiropoulou, V

dc.contributor.author	Roubani-Kalantzopoulou, F	en
dc.contributor.author	Kalogirou, E	en
dc.contributor.author	Kalantzopoulos, A	en
dc.contributor.author	Metaxa, H	en
dc.contributor.author	Thede, R	en
dc.contributor.author	Katsanos, NA	en
dc.contributor.author	Sotiropoulou, V	en
dc.date.accessioned	2014-03-01T01:12:32Z
dc.date.available	2014-03-01T01:12:32Z
dc.date.issued	1997	en
dc.identifier.issn	0009-5893	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/12122
dc.subject	Gas chromatography	en
dc.subject	Rate constants	en
dc.subject	Reaction orders	en
dc.subject	Reversed-flow technique	en
dc.subject.classification	Biochemical Research Methods	en
dc.subject.classification	Chemistry, Analytical	en
dc.subject.other	hydrocarbon	en
dc.subject.other	nitrogen dioxide	en
dc.subject.other	article	en
dc.subject.other	chemical reaction kinetics	en
dc.subject.other	gas chromatography	en
dc.subject.other	mathematics	en
dc.subject.other	priority journal	en
dc.subject.other	technique	en
dc.subject.other	theory	en
dc.title	A differential method for the analysis of chemical kinetics results based on reversed-flow gas chromatography	en
heal.type	journalArticle	en
heal.identifier.primary	10.1007/BF02495328	en
heal.identifier.secondary	http://dx.doi.org/10.1007/BF02495328	en
heal.language	English	en
heal.publicationDate	1997	en
heal.abstract	The reversed-flow gas chromatographic technique has been applied to the determination of the apparent rate constant and the reaction order of a reaction between two gases or vapors. For seven hydrocarbons (ethane, ethene, ethyne, propene, butene, benzene and toluene) reacting with nitrogen dioxide, the above mentioned kinetic parameters have been determined. For these determinations, the necessary mathematical formulation of the problem has been written and solved, leading to simple expressions which describe the height of the chromatographic sample peaks as a function of time.	en
heal.publisher	VIEWEG	en
heal.journalName	Chromatographia	en
dc.identifier.doi	10.1007/BF02495328	en
dc.identifier.isi	ISI:A1997XT60200011	en
dc.identifier.volume	46	en
dc.identifier.issue	3-4	en
dc.identifier.spage	161	en
dc.identifier.epage	169	en