Chemiluminescence of photolyzed or radiolyzed acridine

Papadopoulos, K; Dimotikali, D; Nikokavouras, J

dc.contributor.author	Papadopoulos, K	en
dc.contributor.author	Dimotikali, D	en
dc.contributor.author	Nikokavouras, J	en
dc.date.accessioned	2014-03-01T01:12:40Z
dc.date.available	2014-03-01T01:12:40Z
dc.date.issued	1997	en
dc.identifier.issn	1010-6030	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/12198
dc.subject	Acridine	en
dc.subject	Aminomethylation	en
dc.subject	Chemiluminescence	en
dc.subject	Photolysis	en
dc.subject	Radiolysis	en
dc.subject.classification	Chemistry, Physical	en
dc.subject.other	RESONANCE	en
dc.subject.other	AMIDES	en
dc.title	Chemiluminescence of photolyzed or radiolyzed acridine	en
heal.type	journalArticle	en
heal.identifier.primary	10.1016/S1010-6030(96)04504-2	en
heal.identifier.secondary	http://dx.doi.org/10.1016/S1010-6030(96)04504-2	en
heal.language	English	en
heal.publicationDate	1997	en
heal.abstract	The exposure of acridine in N,N-dialkylamides to sunlight or Co-60 gamma-radiation gives 9-substituted aminomethylacridan derivatives in high yields. The mechanism of the aminomethylation reactions is discussed. The addition of strong bases such as hydrides, or alkoxides in the presence of atmospheric oxygen to the reaction mixtures results in very efficient chemiluminescence. Quantum yields are in the order of 0.3 mol einstein(-1) for the photolysis and are as high as 7X10(-3) einstein mol(-1) for the chemiluminescence. Both the radiolysis and the radiolysis/chemiluminescence reactions constitute prospective radiation dosemeters.	en
heal.publisher	ELSEVIER SCIENCE SA LAUSANNE	en
heal.journalName	Journal of Photochemistry and Photobiology A: Chemistry	en
dc.identifier.doi	10.1016/S1010-6030(96)04504-2	en
dc.identifier.isi	ISI:A1997WZ54900008	en
dc.identifier.volume	103	en
dc.identifier.issue	1-2	en
dc.identifier.spage	51	en
dc.identifier.epage	55	en