Chromatographic study of the influence of nitrogen dioxide on the reactions between volatile hydrocarbons and inorganic pigments

Zahariou-Rakanta, H; Kalantzopoulos, A; Roubani-Kalantzopoulou, F

dc.contributor.author	Zahariou-Rakanta, H	en
dc.contributor.author	Kalantzopoulos, A	en
dc.contributor.author	Roubani-Kalantzopoulou, F	en
dc.date.accessioned	2014-03-01T01:12:40Z
dc.date.available	2014-03-01T01:12:40Z
dc.date.issued	1997	en
dc.identifier.issn	0021-9673	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/12199
dc.subject	Adsorption isotherms	en
dc.subject	Hydrocarbon	en
dc.subject	Kinetic studies	en
dc.subject	Nitrogen dioxide	en
dc.subject	Pigments	en
dc.subject	Reaction kinetics	en
dc.subject.classification	Biochemical Research Methods	en
dc.subject.classification	Chemistry, Analytical	en
dc.subject.other	cadmium sulfide	en
dc.subject.other	hydrocarbon	en
dc.subject.other	metal oxide	en
dc.subject.other	nitrogen dioxide	en
dc.subject.other	pigment	en
dc.subject.other	adsorption	en
dc.subject.other	air pollution	en
dc.subject.other	article	en
dc.subject.other	chemical reaction kinetics	en
dc.subject.other	drug interaction	en
dc.subject.other	mathematical model	en
dc.subject.other	priority journal	en
dc.subject.other	reaction analysis	en
dc.title	Chromatographic study of the influence of nitrogen dioxide on the reactions between volatile hydrocarbons and inorganic pigments	en
heal.type	journalArticle	en
heal.identifier.primary	10.1016/S0021-9673(97)00340-3	en
heal.identifier.secondary	http://dx.doi.org/10.1016/S0021-9673(97)00340-3	en
heal.language	English	en
heal.publicationDate	1997	en
heal.abstract	Deposition velocities, V-d, reaction probabilities, gamma, and local adsorption parameters, k(1), describing the isotherms of ethane, ethene, ethyne, propene and 1-butene onto three solid pigments (PbO, Fe2O3, CdS) have been determined in the absence and in the presence of NO2, together with the surface reaction rare constant, k(2), and the desorption rate constant, k(-1). The calculations are based on experimental adsorption isotherms, since the linear adsorption model is not a very good approximation for inorganic solids like those mentioned above. The important result found is the effect of NO, on the values of the parameters V-d, gamma, k(1), k(-1) and k(2) in most cases. (C) 1997 Elsevier Science B.V.	en
heal.publisher	ELSEVIER SCIENCE BV	en
heal.journalName	Journal of Chromatography A	en
dc.identifier.doi	10.1016/S0021-9673(97)00340-3	en
dc.identifier.isi	ISI:A1997XT07000009	en
dc.identifier.volume	776	en
dc.identifier.issue	2	en
dc.identifier.spage	275	en
dc.identifier.epage	282	en