Raman spectra and conformational analysis of long-methylene-chain diamine-copper complexes

Anastassopoulou, JD; Berjot, M; Marx, J; Paleos, CM; Theophanides, T; Alix, AJP

dc.contributor.author	Anastassopoulou, JD	en
dc.contributor.author	Berjot, M	en
dc.contributor.author	Marx, J	en
dc.contributor.author	Paleos, CM	en
dc.contributor.author	Theophanides, T	en
dc.contributor.author	Alix, AJP	en
dc.date.accessioned	2014-03-01T01:13:17Z
dc.date.available	2014-03-01T01:13:17Z
dc.date.issued	1997	en
dc.identifier.issn	0022-2860	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/12411
dc.subject	Conformational analysis	en
dc.subject	Methylene diamine-copper complexes	en
dc.subject	Raman spectroscopy	en
dc.subject.classification	Chemistry, Physical	en
dc.subject.other	H STRETCHING REGION	en
dc.subject.other	POLYMETHYLENE CHAIN	en
dc.title	Raman spectra and conformational analysis of long-methylene-chain diamine-copper complexes	en
heal.type	journalArticle	en
heal.identifier.primary	10.1016/S0022-2860(97)00103-8	en
heal.identifier.secondary	http://dx.doi.org/10.1016/S0022-2860(97)00103-8	en
heal.language	English	en
heal.publicationDate	1997	en
heal.abstract	Solid powders of long methylene chain diamines NH2-(CH2)(n)-NH2 with n = 10, 12, and their newly synthesized copper complexes were studied by laser visible Raman spectroscopy. In this study, we mainly focus on the intensity variations of both the symmetrical and anti-symmetrical stretching vibrational modes of the CH2 groups situated in the high-frequency range 2800-3000 cm(-1) and on the skeletal vibrations (C-C bonding) in the region 1050-1150 cm(-1), which shows an unusual behaviour upon complexation of the diamines with the copper ion. (C) 1997 Elsevier Science B.V.	en
heal.publisher	ELSEVIER SCIENCE BV	en
heal.journalName	Journal of Molecular Structure	en
dc.identifier.doi	10.1016/S0022-2860(97)00103-8	en
dc.identifier.isi	ISI:A1997YF95200004	en
dc.identifier.volume	415	en
dc.identifier.issue	3	en
dc.identifier.spage	225	en
dc.identifier.epage	237	en