Benzene and toluene influence with or without nitrogen dioxide on inorganic pigments of works of art

Kalantzopoulos, A; Birbatakoy, S; Roubani-Kalantzopoulou, F

dc.contributor.author	Kalantzopoulos, A	en
dc.contributor.author	Birbatakoy, S	en
dc.contributor.author	Roubani-Kalantzopoulou, F	en
dc.date.accessioned	2014-03-01T01:13:36Z
dc.date.available	2014-03-01T01:13:36Z
dc.date.issued	1998	en
dc.identifier.issn	1352-2310	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/12605
dc.subject	Deposition velocity of benzene	en
dc.subject	Deposition velocity of toluene	en
dc.subject	Pigments	en
dc.subject	Reaction probability with inorganic oxides	en
dc.subject	RF-GC technique	en
dc.subject.classification	Environmental Sciences	en
dc.subject.classification	Meteorology & Atmospheric Sciences	en
dc.subject.other	Chromium oxide	en
dc.subject.other	Lead oxide	en
dc.subject.other	Adsorption isotherms	en
dc.subject.other	Benzene	en
dc.subject.other	Chromium compounds	en
dc.subject.other	Desorption	en
dc.subject.other	Iron oxides	en
dc.subject.other	Lead compounds	en
dc.subject.other	Nitrogen oxides	en
dc.subject.other	Pigments	en
dc.subject.other	Titanium dioxide	en
dc.subject.other	Toluene	en
dc.subject.other	Zinc oxide	en
dc.subject.other	Air pollution	en
dc.subject.other	benzene	en
dc.subject.other	iron oxide	en
dc.subject.other	lead oxide	en
dc.subject.other	nitrogen dioxide	en
dc.subject.other	pigment	en
dc.subject.other	titanium dioxide	en
dc.subject.other	toluene	en
dc.subject.other	zinc oxide	en
dc.subject.other	art	en
dc.subject.other	benzene	en
dc.subject.other	nitrogen dioxide	en
dc.subject.other	pigment	en
dc.subject.other	toluene	en
dc.subject.other	adsorption	en
dc.subject.other	air pollution	en
dc.subject.other	art	en
dc.subject.other	article	en
dc.subject.other	chemical reaction	en
dc.subject.other	desorption	en
dc.subject.other	gas chromatography	en
dc.subject.other	priority journal	en
dc.subject.other	probability	en
dc.title	Benzene and toluene influence with or without nitrogen dioxide on inorganic pigments of works of art	en
heal.type	journalArticle	en
heal.identifier.primary	10.1016/S1352-2310(97)00478-0	en
heal.identifier.secondary	http://dx.doi.org/10.1016/S1352-2310(97)00478-0	en
heal.language	English	en
heal.publicationDate	1998	en
heal.abstract	The interaction of benzene and toluene on five known pigments, namely ZnO, PbO, Fe2O3 Cr2O3 and TiO2 has been studied, in the presence as well as in the absence of nitrogen dioxide. The following physicochemical constants have been determined and therefore the materials' behaviour in such a polluted atmosphere is concluded: (1) the dynamic adsorption rate constant of the analyte pollutant, describing its experimental isotherm on the surface of the material varying with the time; (2) the desorption rate constant of the pollutant from the solid surface;(3) the rate constant of a possible surface reaction of the adsorbed analyte (first or pseudo-first order); (4) the overall deposition velocity of the pollutant; (5) the reaction probability of the pollutant on the material; and (6) the apparent rate constant of a possible chemical reaction of each aromatic pollutant with nitrogen dioxide, taking place above the material and simultaneously with the heterogeneous one. The contribution of the above parameters to the elucidation of the mechanism of deterioration of various works of art in museums is significant, as one can see. (C) 1998 Elsevier Science Ltd. All rights reserved.	en
heal.publisher	PERGAMON-ELSEVIER SCIENCE LTD	en
heal.journalName	Atmospheric Environment	en
dc.identifier.doi	10.1016/S1352-2310(97)00478-0	en
dc.identifier.isi	ISI:000073711600016	en
dc.identifier.volume	32	en
dc.identifier.issue	10	en
dc.identifier.spage	1811	en
dc.identifier.epage	1816	en