Photo- and radiochemiluminescence: Reductive chemiluminescence of lucigenin by photo- or radiooxygenated amines and amides

Papadopoulos, K; Triantis, T; Dimotikali, D; Nikokavouras, J

dc.contributor.author	Papadopoulos, K	en
dc.contributor.author	Triantis, T	en
dc.contributor.author	Dimotikali, D	en
dc.contributor.author	Nikokavouras, J	en
dc.date.accessioned	2014-03-01T01:15:03Z
dc.date.available	2014-03-01T01:15:03Z
dc.date.issued	1999	en
dc.identifier.issn	1010-6030	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/13309
dc.subject	Chemiluminescence	en
dc.subject	Lucigenin	en
dc.subject	Photolysis	en
dc.subject	Radiolysis	en
dc.subject.classification	Chemistry, Physical	en
dc.subject.other	ELECTRON-SPIN RESONANCE	en
dc.subject.other	SUPEROXIDE	en
dc.subject.other	LUCIGENIN	en
dc.subject.other	RADICALS	en
dc.subject.other	CHEMILUMINESCENCE	en
dc.subject.other	NUCLEOPHILES	en
dc.subject.other	AMINES	en
dc.title	Photo- and radiochemiluminescence: Reductive chemiluminescence of lucigenin by photo- or radiooxygenated amines and amides	en
heal.type	journalArticle	en
heal.identifier.primary	10.1016/S1010-6030(99)00067-2	en
heal.identifier.secondary	http://dx.doi.org/10.1016/S1010-6030(99)00067-2	en
heal.language	English	en
heal.publicationDate	1999	en
heal.abstract	Addition of photo- or radiooxygenated amines or N,N-dialkylamides to aqueous lucigenin results in efficient chemiluminescence. Chemiluminescence quantum yields for amines are two orders of magnitude higher than those of dialkylamides for the same illumination or irradiation time and can become as high as 4 x 10(-3) einstein/mol. The mechanisms of the photo- or radiooxygenation and chemiluminescence are discussed. The combined photolysis or radiolysis-chemiluminescence reactions constitute light storage systems and prospective radiation dosemeters. (C) 1999 Elsevier Science S.A. All rights reserved.	en
heal.publisher	ELSEVIER SCIENCE SA	en
heal.journalName	Journal of Photochemistry and Photobiology A: Chemistry	en
dc.identifier.doi	10.1016/S1010-6030(99)00067-2	en
dc.identifier.isi	ISI:000080889700012	en
dc.identifier.volume	124	en
dc.identifier.issue	1-2	en
dc.identifier.spage	85	en
dc.identifier.epage	90	en