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Prediction of phase equilibria in water/alcohol/alkane systems

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dc.contributor.author Voutsas, EC en
dc.contributor.author Yakoumis, IV en
dc.contributor.author Tassios, DP en
dc.date.accessioned 2014-03-01T01:15:04Z
dc.date.available 2014-03-01T01:15:04Z
dc.date.issued 1999 en
dc.identifier.issn 0378-3812 en
dc.identifier.uri https://dspace.lib.ntua.gr/xmlui/handle/123456789/13323
dc.subject Associating fluids en
dc.subject Equation of state en
dc.subject Liquid-liquid equilibrium en
dc.subject Vapor-liquid equilibrium en
dc.subject.classification Thermodynamics en
dc.subject.classification Chemistry, Physical en
dc.subject.classification Engineering, Chemical en
dc.subject.other Alcohols en
dc.subject.other Association reactions en
dc.subject.other Binary mixtures en
dc.subject.other Equations of state en
dc.subject.other Paraffins en
dc.subject.other Water en
dc.subject.other Associating fluids en
dc.subject.other Liquid-liquid equilibrium en
dc.subject.other Ternary associating mixtures en
dc.subject.other Vapor liquid equilibrium en
dc.subject.other Phase equilibria en
dc.subject.other alcohol en
dc.subject.other alkane en
dc.subject.other water en
dc.subject.other conference paper en
dc.subject.other liquid en
dc.subject.other mathematical analysis en
dc.subject.other phase transition en
dc.subject.other prediction en
dc.subject.other vapor en
dc.title Prediction of phase equilibria in water/alcohol/alkane systems en
heal.type journalArticle en
heal.identifier.primary 10.1016/S0378-3812(99)00131-4 en
heal.identifier.secondary http://dx.doi.org/10.1016/S0378-3812(99)00131-4 en
heal.language English en
heal.publicationDate 1999 en
heal.abstract The Cubic Plus Association Equation of State (CPA EoS) is applied to the prediction of Vapor-Liquid Equilibrium (VLE) and Liquid-Liquid Equilibrium (LLE) in ternary associating mixtures containing water, alcohols and alkanes. The appropriate set of combining rules for the cross-association energy and volume parameters of the EoS is identified by evaluating the performance of four such sets in the correlation of VLE and LLE for water/alcohol mixtures. Using only one interaction parameter per binary mixture, in the physical part of the EoS, CPA gives very satisfactory predictions of ternary VLE and LLE. (C) 1999 Elsevier Science B.V. All rights reserved. en
heal.publisher ELSEVIER SCIENCE BV en
heal.journalName Fluid Phase Equilibria en
dc.identifier.doi 10.1016/S0378-3812(99)00131-4 en
dc.identifier.isi ISI:000080955200016 en
dc.identifier.volume 158-160 en
dc.identifier.spage 151 en
dc.identifier.epage 163 en


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