dc.contributor.author |
Shilov, VV |
en |
dc.contributor.author |
Gomza, YuP |
en |
dc.contributor.author |
Klepko, VV |
en |
dc.contributor.author |
Slisenko, VI |
en |
dc.contributor.author |
Vasil'kevich, AA |
en |
dc.contributor.author |
Shembel, EM |
en |
dc.contributor.author |
Burmistr, MV |
en |
dc.contributor.author |
Pissis, P |
en |
dc.date.accessioned |
2014-03-01T01:17:56Z |
|
dc.date.available |
2014-03-01T01:17:56Z |
|
dc.date.issued |
2002 |
en |
dc.identifier.issn |
1070-9878 |
en |
dc.identifier.uri |
https://dspace.lib.ntua.gr/xmlui/handle/123456789/14710 |
|
dc.subject |
Glass Transition |
en |
dc.subject |
Neutron Scattering |
en |
dc.subject |
X-ray Scattering |
en |
dc.subject |
Propylene Carbonate |
en |
dc.subject.classification |
Engineering, Electrical & Electronic |
en |
dc.subject.classification |
Physics, Applied |
en |
dc.subject.other |
Addition reactions |
en |
dc.subject.other |
Composition |
en |
dc.subject.other |
Electric conductivity of solids |
en |
dc.subject.other |
Glass transition |
en |
dc.subject.other |
Lithium compounds |
en |
dc.subject.other |
Molecules |
en |
dc.subject.other |
Morphology |
en |
dc.subject.other |
Thermodynamic properties |
en |
dc.subject.other |
X ray scattering |
en |
dc.subject.other |
Micropores |
en |
dc.subject.other |
Polymer gel electrolytes |
en |
dc.subject.other |
Propylene carbonate |
en |
dc.subject.other |
Quasi-elastic neutron scattering |
en |
dc.subject.other |
Polyvinyl chlorides |
en |
dc.title |
Gel electrolyte system based on polyvinyl chloride with addition of LiClO4/propylene carbonate: Structure, morphology, thermal and conductivity properties |
en |
heal.type |
journalArticle |
en |
heal.identifier.primary |
10.1109/TDEI.2002.1024432 |
en |
heal.identifier.secondary |
http://dx.doi.org/10.1109/TDEI.2002.1024432 |
en |
heal.language |
English |
en |
heal.publicationDate |
2002 |
en |
heal.abstract |
X-ray scattering, calorimetric, and quasi-elastic neutron scattering (QENS) investigations of the polymer gel electrolytes based on 20% PVC, containing 80% of propylene carbonate (PC) -LiClO4 solution as a liquid phase were made. It was established, that after incorporating PC into the micropores of PVC gels the glass transition of PC increased by 3 K. This is, evidently, a reflection of an effect of confining liquid PC in the pores of PVC microphase-separated morphology. Addition of salt to the PVC-PC system results in raising T-g of both them pure PC and PVC-PC gel by 10 K. The SAXS data of pure PVC and PVC-PC and PVC-PC-LiClO4 indicate that the gels based on PVC consist of microdomains of a different composition. Single-particle and collective dynamics of solvent molecules in free state and in the pores of polymer gels based on PVC were studied by quasi-elastic neutron scattering technique. |
en |
heal.publisher |
IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC |
en |
heal.journalName |
IEEE Transactions on Dielectrics and Electrical Insulation |
en |
dc.identifier.doi |
10.1109/TDEI.2002.1024432 |
en |
dc.identifier.isi |
ISI:000177373600008 |
en |
dc.identifier.volume |
9 |
en |
dc.identifier.issue |
4 |
en |
dc.identifier.spage |
551 |
en |
dc.identifier.epage |
554 |
en |