Gel electrolyte system based on polyvinyl chloride with addition of LiClO4/propylene carbonate: Structure, morphology, thermal and conductivity properties

Shilov, VV; Gomza, YuP; Klepko, VV; Slisenko, VI; Vasil'kevich, AA; Shembel, EM; Burmistr, MV; Pissis, P

dc.contributor.author	Shilov, VV	en
dc.contributor.author	Gomza, YuP	en
dc.contributor.author	Klepko, VV	en
dc.contributor.author	Slisenko, VI	en
dc.contributor.author	Vasil'kevich, AA	en
dc.contributor.author	Shembel, EM	en
dc.contributor.author	Burmistr, MV	en
dc.contributor.author	Pissis, P	en
dc.date.accessioned	2014-03-01T01:17:56Z
dc.date.available	2014-03-01T01:17:56Z
dc.date.issued	2002	en
dc.identifier.issn	1070-9878	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/14710
dc.subject	Glass Transition	en
dc.subject	Neutron Scattering	en
dc.subject	X-ray Scattering	en
dc.subject	Propylene Carbonate	en
dc.subject.classification	Engineering, Electrical & Electronic	en
dc.subject.classification	Physics, Applied	en
dc.subject.other	Addition reactions	en
dc.subject.other	Composition	en
dc.subject.other	Electric conductivity of solids	en
dc.subject.other	Glass transition	en
dc.subject.other	Lithium compounds	en
dc.subject.other	Molecules	en
dc.subject.other	Morphology	en
dc.subject.other	Thermodynamic properties	en
dc.subject.other	X ray scattering	en
dc.subject.other	Micropores	en
dc.subject.other	Polymer gel electrolytes	en
dc.subject.other	Propylene carbonate	en
dc.subject.other	Quasi-elastic neutron scattering	en
dc.subject.other	Polyvinyl chlorides	en
dc.title	Gel electrolyte system based on polyvinyl chloride with addition of LiClO4/propylene carbonate: Structure, morphology, thermal and conductivity properties	en
heal.type	journalArticle	en
heal.identifier.primary	10.1109/TDEI.2002.1024432	en
heal.identifier.secondary	http://dx.doi.org/10.1109/TDEI.2002.1024432	en
heal.language	English	en
heal.publicationDate	2002	en
heal.abstract	X-ray scattering, calorimetric, and quasi-elastic neutron scattering (QENS) investigations of the polymer gel electrolytes based on 20% PVC, containing 80% of propylene carbonate (PC) -LiClO4 solution as a liquid phase were made. It was established, that after incorporating PC into the micropores of PVC gels the glass transition of PC increased by 3 K. This is, evidently, a reflection of an effect of confining liquid PC in the pores of PVC microphase-separated morphology. Addition of salt to the PVC-PC system results in raising T-g of both them pure PC and PVC-PC gel by 10 K. The SAXS data of pure PVC and PVC-PC and PVC-PC-LiClO4 indicate that the gels based on PVC consist of microdomains of a different composition. Single-particle and collective dynamics of solvent molecules in free state and in the pores of polymer gels based on PVC were studied by quasi-elastic neutron scattering technique.	en
heal.publisher	IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC	en
heal.journalName	IEEE Transactions on Dielectrics and Electrical Insulation	en
dc.identifier.doi	10.1109/TDEI.2002.1024432	en
dc.identifier.isi	ISI:000177373600008	en
dc.identifier.volume	9	en
dc.identifier.issue	4	en
dc.identifier.spage	551	en
dc.identifier.epage	554	en