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Lateral molecular interaction on heterogeneous surfaces experimentally measured

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dc.contributor.author Katsanos, NA en
dc.contributor.author Roubani-Kalantzopoulou, F en
dc.contributor.author Iliopoulou, E en
dc.contributor.author Bassiotis, I en
dc.contributor.author Siokos, V en
dc.contributor.author Vrahatis, MN en
dc.contributor.author Plagianakos, VP en
dc.date.accessioned 2014-03-01T01:18:02Z
dc.date.available 2014-03-01T01:18:02Z
dc.date.issued 2002 en
dc.identifier.issn 09277757 en
dc.identifier.uri https://dspace.lib.ntua.gr/xmlui/handle/123456789/14758
dc.subject Adsorption isotherms en
dc.subject Atom-solid interactions en
dc.subject Physical adsorption en
dc.subject Surface energy en
dc.subject.other Adsorption en
dc.subject.other Butenes en
dc.subject.other Gas chromatography en
dc.subject.other Lime en
dc.subject.other Molecules en
dc.subject.other Molecular interactions en
dc.subject.other Surface chemistry en
dc.subject.other alkene derivative en
dc.subject.other cadmium sulfide en
dc.subject.other calcium oxide en
dc.subject.other ethane en
dc.subject.other adsorption en
dc.subject.other article en
dc.subject.other calculation en
dc.subject.other energy en
dc.subject.other gas chromatography en
dc.subject.other isotherm en
dc.subject.other methodology en
dc.subject.other molecular interaction en
dc.subject.other priority journal en
dc.subject.other surface property en
dc.title Lateral molecular interaction on heterogeneous surfaces experimentally measured en
heal.type journalArticle en
heal.identifier.primary 10.1016/S0927-7757(01)01036-6 en
heal.identifier.secondary http://dx.doi.org/10.1016/S0927-7757(01)01036-6 en
heal.publicationDate 2002 en
heal.abstract Using inverse gas chromatography, the added to ε differential energy of adsorption due to lateral interactions of molecules adsorbed on a heterogeneous solid surface was determined. The method was applied to three gas/solid systems, namely, 1-butene/cadmium sulphide, ethane/calcium oxide, and trans-2-butene/marble. By plotting the dimensionless lateral interaction energy against time t in parallel with the energy distribution function against ε and t, the appearance of curves against t is quite similar in all three systems. This was explained on the basis of Bakaev and Steele model for adsorption sites, i.e. on the existence of three kinds of sites. © 2002 Elsevier Science B.V. All rights reserved. en
heal.journalName Colloids and Surfaces A: Physicochemical and Engineering Aspects en
dc.identifier.doi 10.1016/S0927-7757(01)01036-6 en
dc.identifier.volume 201 en
dc.identifier.issue 1-3 en
dc.identifier.spage 173 en
dc.identifier.epage 180 en


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