Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds: XXXVII. 1 Effect of Nucleofuge and Solvent of the Relative Rates of Heterolysis of 1Halo1-methylcyclopentanes and 1Halo1-methylcyclohexanes. Correlation Analysis of Solvation Effects

Dvorko, G; Koshchii, I; Ponomareva, E

dc.contributor.author	Dvorko, G	en
dc.contributor.author	Koshchii, I	en
dc.contributor.author	Ponomareva, E	en
dc.date.accessioned	2014-03-01T01:19:05Z
dc.date.available	2014-03-01T01:19:05Z
dc.date.issued	2003	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/15372
dc.subject	Correlation Analysis	en
dc.subject	Kinetics	en
dc.subject	Relative Rate	en
dc.title	Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds: XXXVII. 1 Effect of Nucleofuge and Solvent of the Relative Rates of Heterolysis of 1Halo1-methylcyclopentanes and 1Halo1-methylcyclohexanes. Correlation Analysis of Solvation Effects	en
heal.type	journalArticle	en
heal.identifier.primary	10.1023/B:RUGC.0000015993.04565.ee	en
heal.identifier.secondary	http://dx.doi.org/10.1023/B:RUGC.0000015993.04565.ee	en
heal.publicationDate	2003	en
heal.abstract	The effect of solvent ionizing ability on heterolysis rate enhances in the series 1-chloro-1-methylcyclohexane < 1-bromo-1-methylcyclohexane ˜ 1-chloro-1-methylcyclopentane < 1-bromo-1-methyl- cyclopentane. The lower sensitivity of cyclohexyl substrates compared with cyclopentyl is determined by conformational effects. Bromides are more sensitive to solvent effects than chlorides because of the stronger polarizability of the C-Br bond.	en
heal.journalName	Russian Journal of General Chemistry	en
dc.identifier.doi	10.1023/B:RUGC.0000015993.04565.ee	en