Benzene and toluene influence with or without nitrogen dioxide on inorganic pigments of works of art-Part II

Agelakopoulou, T; Bassiotis, I; Metaxa, E; Roubani-Kalantzopoulou, F

dc.contributor.author	Agelakopoulou, T	en
dc.contributor.author	Bassiotis, I	en
dc.contributor.author	Metaxa, E	en
dc.contributor.author	Roubani-Kalantzopoulou, F	en
dc.date.accessioned	2014-03-01T01:25:58Z
dc.date.available	2014-03-01T01:25:58Z
dc.date.issued	2007	en
dc.identifier.issn	1352-2310	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/17854
dc.subject	Adsorption	en
dc.subject	Benzene	en
dc.subject	Inverse Gas Chromatography	en
dc.subject	Local parameters	en
dc.subject	Reversed Flow-Gas Chromatography	en
dc.subject	Toluene	en
dc.subject.classification	Environmental Sciences	en
dc.subject.classification	Meteorology & Atmospheric Sciences	en
dc.subject.other	Adsorption	en
dc.subject.other	Economic and social effects	en
dc.subject.other	Gas chromatography	en
dc.subject.other	Monolayers	en
dc.subject.other	Nitrogen oxides	en
dc.subject.other	Pigments	en
dc.subject.other	Toluene	en
dc.subject.other	Inverse Gas Chromatography	en
dc.subject.other	Local parameters	en
dc.subject.other	Reversed Flow-Gas Chromatography	en
dc.subject.other	Benzene	en
dc.subject.other	benzene	en
dc.subject.other	chromium derivative	en
dc.subject.other	inorganic compound	en
dc.subject.other	lead oxide	en
dc.subject.other	nitrogen dioxide	en
dc.subject.other	pigment	en
dc.subject.other	titanium dioxide	en
dc.subject.other	toluene	en
dc.subject.other	volatile agent	en
dc.subject.other	adsorption	en
dc.subject.other	atmospheric chemistry	en
dc.subject.other	atmospheric pollution	en
dc.subject.other	benzene	en
dc.subject.other	gas chromatography	en
dc.subject.other	nitrogen dioxide	en
dc.subject.other	oxide group	en
dc.subject.other	physicochemical property	en
dc.subject.other	socioeconomic impact	en
dc.subject.other	toluene	en
dc.subject.other	adsorption	en
dc.subject.other	air pollutant	en
dc.subject.other	air pollution	en
dc.subject.other	art	en
dc.subject.other	article	en
dc.subject.other	density	en
dc.subject.other	energy	en
dc.subject.other	gas chromatography	en
dc.subject.other	physical chemistry	en
dc.subject.other	priority journal	en
dc.title	Benzene and toluene influence with or without nitrogen dioxide on inorganic pigments of works of art-Part II	en
heal.type	journalArticle	en
heal.identifier.primary	10.1016/j.atmosenv.2006.10.002	en
heal.identifier.secondary	http://dx.doi.org/10.1016/j.atmosenv.2006.10.002	en
heal.language	English	en
heal.publicationDate	2007	en
heal.abstract	Air pollution has a great impact on the social and economic aspects all over the world. In order to account the human interaction with the atmospheric environment, a suitable scientific basis is needed. That is why six physicochemical quantities have been determined in a previous work for each one heterogeneous system between organic volatile pollutants and oxide-pigments of works of art. This investigation is extended in order to determine experimentally five new ones. Thus, a more precise contribution to the elucidation of the mechanism of the deterioration of various works of art in museums is achieved. These physicochemical quantities are: (1) local adsorption energies, (2) local monolayer capacities, (3) local adsorption isotherms, (4) density probability function, and (5) pollutant concentration on the oxide-pigment at equilibrium. All these adsorption parameters mentioned above have been calculated as a function of experimental time for the systems: C6H6/TiO2, C6H6/NO2/TiO2, C6H6/Cr2O3, C6H6/NO2/Cr2O3, C6H5CH3/TiO2, C6H5CH3/NO2/TiO2, C6H5CH3/Cr2O3, C6H5CH3/NO2/Cr2O3, C6H6/PbO, C6H6/NO2/PbO, C6H5CH3/PbO, and C6H5CH3/NO2/PbO for the first time. Thus, in this work we shall stress the recent new aspect of Reversed Flow(Inverse) Gas Chromatography (RF-CYC or RF-IGC), i.e. the time-resolved chromatography related to the evaluation of some important adsorption parameters. Gas Chromatography is a promising meeting place of surface science and atmospheric chemistry. (c) 2006 Elsevier Ltd. All rights reserved.	en
heal.publisher	PERGAMON-ELSEVIER SCIENCE LTD	en
heal.journalName	Atmospheric Environment	en
dc.identifier.doi	10.1016/j.atmosenv.2006.10.002	en
dc.identifier.isi	ISI:000244549600017	en
dc.identifier.volume	41	en
dc.identifier.issue	9	en
dc.identifier.spage	2009	en
dc.identifier.epage	2018	en