Supramolecular assemblies of nucleobase derivative 1-Mecyt with Mg(II) and Ni(II) and solid-state transformation of Ni(II) phase: A comprehensive evidence of their different reactivity toward 1-Mecyt [1-Mecyt = 1-Methylcytosine]

Mastropietro, TF; Armentano, D; Marino, N; De Munno, G; Anastassopoulou, J; Theophanides, T

dc.contributor.author	Mastropietro, TF	en
dc.contributor.author	Armentano, D	en
dc.contributor.author	Marino, N	en
dc.contributor.author	De Munno, G	en
dc.contributor.author	Anastassopoulou, J	en
dc.contributor.author	Theophanides, T	en
dc.date.accessioned	2014-03-01T01:27:21Z
dc.date.available	2014-03-01T01:27:21Z
dc.date.issued	2007	en
dc.identifier.issn	1528-7483	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/18413
dc.subject.classification	Chemistry, Multidisciplinary	en
dc.subject.classification	Crystallography	en
dc.subject.classification	Materials Science, Multidisciplinary	en
dc.subject.other	TRANSITION-METAL SALTS	en
dc.subject.other	X-RAY STRUCTURE	en
dc.subject.other	CRYSTAL-STRUCTURES	en
dc.subject.other	PLATINUM(II) COMPLEXES	en
dc.subject.other	MOLECULAR-STRUCTURE	en
dc.subject.other	NUCLEIC BASES	en
dc.subject.other	CYTOSINE	en
dc.subject.other	BINDING	en
dc.subject.other	MODEL	en
dc.subject.other	1-METHYLCYTOSINE	en
dc.title	Supramolecular assemblies of nucleobase derivative 1-Mecyt with Mg(II) and Ni(II) and solid-state transformation of Ni(II) phase: A comprehensive evidence of their different reactivity toward 1-Mecyt [1-Mecyt = 1-Methylcytosine]	en
heal.type	journalArticle	en
heal.identifier.primary	10.1021/cg060894k	en
heal.identifier.secondary	http://dx.doi.org/10.1021/cg060894k	en
heal.language	English	en
heal.publicationDate	2007	en
heal.abstract	The synthesis and crystal structure of the compounds [Mg(H2O)6(1-Mecyt)2]Cl2 (1), [Ni(H2O)6(1-Mecyt)2]Cl2 (2), and [Ni-(1-Mecyt)2Cl2] (3) (where 1-Mecyt = 1-Methylcytosine) are reported. Compounds 1 and 2 consist of hexaaquo ions, 1-Mecyt molecules, and chloride ions self-assembled through an extended network of hydrogen-bonding interactions. Compound 3 is made of [Ni(1-Mecyt)2Cl2] units, with the 1-Mecyt molecules directly coordinated to the metal centers through the N(3) and O(2) atoms. When crystals of compound 2 are allowed to stand in air for 1 week, a solid transformation occurs. The results of our investigation clearly suggest that a solid-state reaction takes place in 2, leading to 3. © 2007 American Chemical Society.	en
heal.publisher	AMER CHEMICAL SOC	en
heal.journalName	Crystal Growth and Design	en
dc.identifier.doi	10.1021/cg060894k	en
dc.identifier.isi	ISI:000245408400008	en
dc.identifier.volume	7	en
dc.identifier.issue	4	en
dc.identifier.spage	609	en
dc.identifier.epage	612	en