An efficient one pot synthesis of 1,2-bis-(p-aminophenylimino)-acenaphthene, a new compound with significant photoconductive response

Mhaidat, I; Hamilakis, S; Kollia, C; Tsolomitis, A; Loizos, Z

dc.contributor.author	Mhaidat, I	en
dc.contributor.author	Hamilakis, S	en
dc.contributor.author	Kollia, C	en
dc.contributor.author	Tsolomitis, A	en
dc.contributor.author	Loizos, Z	en
dc.date.accessioned	2014-03-01T01:27:53Z
dc.date.available	2014-03-01T01:27:53Z
dc.date.issued	2008	en
dc.identifier.issn	0167-577X	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/18622
dc.subject	π-conjugated system	en
dc.subject	Optoelectronic material	en
dc.subject	Photo resistors	en
dc.subject	Photoconductive switches	en
dc.subject	Photocurrent	en
dc.subject	Photodiodes	en
dc.subject	Sensors	en
dc.subject	Small-molecule organic semiconductor	en
dc.subject	Solar cells	en
dc.subject.classification	Materials Science, Multidisciplinary	en
dc.subject.classification	Physics, Applied	en
dc.subject.other	Arsenic compounds	en
dc.subject.other	Electric conductivity	en
dc.subject.other	Photoconductivity	en
dc.subject.other	Semiconducting cadmium telluride	en
dc.subject.other	Acenaphthene	en
dc.subject.other	Chemical structures	en
dc.subject.other	Low costs	en
dc.subject.other	One pot synthesis	en
dc.subject.other	Photoconductive responses	en
dc.subject.other	Starting materials	en
dc.subject.other	Complexation	en
dc.title	An efficient one pot synthesis of 1,2-bis-(p-aminophenylimino)-acenaphthene, a new compound with significant photoconductive response	en
heal.type	journalArticle	en
heal.identifier.primary	10.1016/j.matlet.2008.06.021	en
heal.identifier.secondary	http://dx.doi.org/10.1016/j.matlet.2008.06.021	en
heal.language	English	en
heal.publicationDate	2008	en
heal.abstract	A significant high photocurrent was observed in a new compound, synthesized by a simple, effective, low cost, and one stage reaction, using as a starting material the acenaphthenquinone, which presents a negligible photoconductivity. Chemical structure of the as-prepared compound was assigned by H-1 and C-13 NMR techniques. IR spectroscopy and elemental analysis. Photoresponse measurements of the substance prepared, isolated and formulated as thin films on titanium substrates, were performed by a solution deposition technique in a photoelectrochemical cell (PEC) under different illumination conditions. The photocurrents observed, significantly high under strong illumination conditions, might be attributed to the structure of the substance prepared which favors the development of an extended pi-conjugated system. Thereby, this product may be useful in devices as organic thin film transistors, on/off sensors, etc. On the other hand, as the compound is potentially polymerized, it seems to be a particularly promising monomer for the preparation of organic conductive polymers, very useful for the development of a large variety of optoelectronic products. (c) 2008 Elsevier B.V. All rights reserved.	en
heal.publisher	ELSEVIER SCIENCE BV	en
heal.journalName	Materials Letters	en
dc.identifier.doi	10.1016/j.matlet.2008.06.021	en
dc.identifier.isi	ISI:000258908600008	en
dc.identifier.volume	62	en
dc.identifier.issue	26	en
dc.identifier.spage	4198	en
dc.identifier.epage	4200	en