Hydrogenation of 1-butene on nanosized Pd/ZnO catalysts

Agelakopoulou, T; Roubani-Kalantzopoulou, F

dc.contributor.author	Agelakopoulou, T	en
dc.contributor.author	Roubani-Kalantzopoulou, F	en
dc.date.accessioned	2014-03-01T01:28:38Z
dc.date.available	2014-03-01T01:28:38Z
dc.date.issued	2008	en
dc.identifier.issn	0021-9673	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/18890
dc.subject	Hydrogenation of 1-butene	en
dc.subject	Identification of chromatographic peaks by RF-IGC	en
dc.subject	Inverse gas chromatography on catalytic studies	en
dc.subject	Isomerization of 1-butene	en
dc.subject	Kinetic constants	en
dc.subject	Surface diffusion coefficient	en
dc.subject.classification	Biochemical Research Methods	en
dc.subject.classification	Chemistry, Analytical	en
dc.subject.other	Addition reactions	en
dc.subject.other	Adsorption	en
dc.subject.other	Butenes	en
dc.subject.other	Catalysis	en
dc.subject.other	Chromatographic analysis	en
dc.subject.other	Curve fitting	en
dc.subject.other	Desorption	en
dc.subject.other	Gas chromatography	en
dc.subject.other	Hydrocarbons	en
dc.subject.other	Hydrogenation	en
dc.subject.other	Microfluidics	en
dc.subject.other	Reaction kinetics	en
dc.subject.other	Surface diffusion	en
dc.subject.other	Surfaces	en
dc.subject.other	Thick films	en
dc.subject.other	Thin films	en
dc.subject.other	(1 1 0) surface	en
dc.subject.other	1 butene (sPB)	en
dc.subject.other	Applied (CO)	en
dc.subject.other	Elsevier (CO)	en
dc.subject.other	Inverse gas chromatography (IGC)	en
dc.subject.other	Nano-sized	en
dc.subject.other	Parallel reactions	en
dc.subject.other	Time periods	en
dc.subject.other	Surface reactions	en
dc.subject.other	1 butene	en
dc.subject.other	alkene derivative	en
dc.subject.other	palladium	en
dc.subject.other	zinc oxide	en
dc.subject.other	accuracy	en
dc.subject.other	adsorption	en
dc.subject.other	article	en
dc.subject.other	catalysis	en
dc.subject.other	catalyst	en
dc.subject.other	desorption	en
dc.subject.other	diffusion	en
dc.subject.other	gas chromatography	en
dc.subject.other	hydrogenation	en
dc.subject.other	priority journal	en
dc.subject.other	Alkenes	en
dc.subject.other	Catalysis	en
dc.subject.other	Chromatography, Gas	en
dc.subject.other	Hydrogenation	en
dc.subject.other	Nanoparticles	en
dc.subject.other	Palladium	en
dc.subject.other	Reproducibility of Results	en
dc.subject.other	Zinc Oxide	en
dc.title	Hydrogenation of 1-butene on nanosized Pd/ZnO catalysts	en
heal.type	journalArticle	en
heal.identifier.primary	10.1016/j.chroma.2008.05.046	en
heal.identifier.secondary	http://dx.doi.org/10.1016/j.chroma.2008.05.046	en
heal.language	English	en
heal.publicationDate	2008	en
heal.abstract	The reaction concerning the hydrogenation of 1-butene has occupied the researchers conducting research based on the method of reversed-flow inverse gas chromatography (RF-IGC), for extended time periods. This work aims to define and record, with the utmost accuracy, the phenomena and their possible parallel reactions. It was a challenge for the RF-IGC, which was met. The venture consisted of many parts. Answers had to be provided to the following questions: (a) Can RF-IGC deal with issues of catalysis? (b) Can RFIGC be applied to thin films? (c) Can RF-IGC identify peaks? (d) Can RF-IGC define the gnostic regions of adsorption, desorption, surface diffusion, surface reaction, the existence of more than one reaction? (e) Can it kinetically follow the above? The answer is certainly yes. The effort made is presented in this work and aims to answer all the above questions. (c) 2008 Elsevier B.V. All rights reserved.	en
heal.publisher	ELSEVIER SCIENCE BV	en
heal.journalName	Journal of Chromatography A	en
dc.identifier.doi	10.1016/j.chroma.2008.05.046	en
dc.identifier.isi	ISI:000257959000014	en
dc.identifier.volume	1200	en
dc.identifier.issue	2	en
dc.identifier.spage	204	en
dc.identifier.epage	210	en