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Benefit of microscopic diffusion measurement for the characterization of nanoporous materials

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dc.contributor.author Karger, J en
dc.contributor.author Caro, J en
dc.contributor.author Cool, P en
dc.contributor.author Coppens, M-O en
dc.contributor.author Jones, D en
dc.contributor.author Kapteijn, F en
dc.contributor.author Rodriguez-Reinoso, F en
dc.contributor.author Stocker, M en
dc.contributor.author Theodorou, D en
dc.contributor.author Vansant, EF en
dc.contributor.author Weitkamp, J en
dc.date.accessioned 2014-03-01T01:29:54Z
dc.date.available 2014-03-01T01:29:54Z
dc.date.issued 2009 en
dc.identifier.issn 0930-7516 en
dc.identifier.uri https://dspace.lib.ntua.gr/xmlui/handle/123456789/19405
dc.subject Diffusion en
dc.subject Interference microscopy en
dc.subject IR-spectroscopy en
dc.subject Nanoporous materials en
dc.subject NMR en
dc.subject Transport resistances en
dc.subject.classification Engineering, Chemical en
dc.subject.other Interference microscopy en
dc.subject.other IR-spectroscopy en
dc.subject.other Nanoporous materials en
dc.subject.other NMR en
dc.subject.other Transport resistances en
dc.subject.other Diffusion en
dc.subject.other Materials properties en
dc.subject.other Nuclear magnetic resonance en
dc.subject.other Plasma interactions en
dc.subject.other Spacecraft instruments en
dc.subject.other Transport properties en
dc.subject.other Microporous materials en
dc.title Benefit of microscopic diffusion measurement for the characterization of nanoporous materials en
heal.type journalArticle en
heal.identifier.primary 10.1002/ceat.200900160 en
heal.identifier.secondary http://dx.doi.org/10.1002/ceat.200900160 en
heal.language English en
heal.publicationDate 2009 en
heal.abstract Detailed knowledge of the transport properties of nanoporous materials is a pre-requisite for their complete characterization and optimum technological exploitation. One of the best ways to attain this information is provided by the ""microscopic"" techniques of diffusion measurement, in particular by the pulsed field gradient technique of NMR and by interference microscopy and IR microscopy. Starting with the measuring principles, the various types of evidence as accessible by these techniques are illustrated. A large variety of host-guest systems with both ordered and random pore networks have been studied, from microporous up to macroporous materials. The information obtained concerns diffusivities in the various pore domains, extra resistances at the interfaces between them and the associated exchange rates. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. en
heal.publisher WILEY-V C H VERLAG GMBH en
heal.journalName Chemical Engineering and Technology en
dc.identifier.doi 10.1002/ceat.200900160 en
dc.identifier.isi ISI:000271008700004 en
dc.identifier.volume 32 en
dc.identifier.issue 10 en
dc.identifier.spage 1494 en
dc.identifier.epage 1511 en


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