One-stage synthesis of poly[(p-phenylimino)-acenaphthene], a new macromolecular material with interesting electric properties

Mhaidat, I; Mergos, JA; Hamilakis, S; Kollia, C; Loizos, Z; Tsolomitis, A; Dervos, CT

dc.contributor.author	Mhaidat, I	en
dc.contributor.author	Mergos, JA	en
dc.contributor.author	Hamilakis, S	en
dc.contributor.author	Kollia, C	en
dc.contributor.author	Loizos, Z	en
dc.contributor.author	Tsolomitis, A	en
dc.contributor.author	Dervos, CT	en
dc.date.accessioned	2014-03-01T01:31:35Z
dc.date.available	2014-03-01T01:31:35Z
dc.date.issued	2009	en
dc.identifier.issn	0167-577X	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/19827
dc.subject	Electrostatic flooring	en
dc.subject	One-stage polymerization	en
dc.subject	Poly-imines	en
dc.subject	Polycondensation	en
dc.subject	Polymeric semiconductors	en
dc.subject.classification	Materials Science, Multidisciplinary	en
dc.subject.classification	Physics, Applied	en
dc.subject.other	Acenaphthene	en
dc.subject.other	Acenaphthenequinone	en
dc.subject.other	FTIR	en
dc.subject.other	Mass spectra	en
dc.subject.other	Mass spectroscopy	en
dc.subject.other	O-dichlorobenzene	en
dc.subject.other	One-stage polymerization	en
dc.subject.other	P-phenylene diamines	en
dc.subject.other	Photoconductive properties	en
dc.subject.other	Poly-imines	en
dc.subject.other	Polycondensation reactions	en
dc.subject.other	Polymeric semiconductors	en
dc.subject.other	Semiconductive	en
dc.subject.other	Small molecules	en
dc.subject.other	Starting materials	en
dc.subject.other	Building materials	en
dc.subject.other	Electric properties	en
dc.subject.other	Electrostatics	en
dc.subject.other	Floors	en
dc.subject.other	Fourier transform infrared spectroscopy	en
dc.subject.other	Macromolecules	en
dc.subject.other	Mass spectrometers	en
dc.subject.other	Mass spectrometry	en
dc.subject.other	Nitrogen compounds	en
dc.subject.other	Photoconductivity	en
dc.subject.other	Polycondensation	en
dc.subject.other	Polymers	en
dc.title	One-stage synthesis of poly[(p-phenylimino)-acenaphthene], a new macromolecular material with interesting electric properties	en
heal.type	journalArticle	en
heal.identifier.primary	10.1016/j.matlet.2009.09.016	en
heal.identifier.secondary	http://dx.doi.org/10.1016/j.matlet.2009.09.016	en
heal.language	English	en
heal.publicationDate	2009	en
heal.abstract	A new macromolecular material, a derivative of 1,2-bis-(p-aminophenylimino)-acenaphthene. was prepared. The monomer above, belonging to the group of small-molecule semiconductors, presents, as we referred in a previous work (Mhaidat [1]), remarkable photoconductive properties. The polymerization, a polycondensation reaction, was achieved in one-stage, using as starting materials acenaphthenequinone and p-phenylenediamine. in the presence of TiCl4 and Dabco as catalysts, into o-dichlorobenzene acting as a solvent. The product obtained was fully characterized with mass spectroscopy, H-1 NMR and FTIR techniques. Mass spectrum permitted the calculation of the polymer's molecular weight, being equal to 1633.85, whereas measurements of electric properties confirmed its semiconductive character. (C) 2009 Elsevier B.V. All rights reserved.	en
heal.publisher	ELSEVIER SCIENCE BV	en
heal.journalName	Materials Letters	en
dc.identifier.doi	10.1016/j.matlet.2009.09.016	en
dc.identifier.isi	ISI:000271127700017	en
dc.identifier.volume	63	en
dc.identifier.issue	29	en
dc.identifier.spage	2587	en
dc.identifier.epage	2590	en