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MOCVD cobalt oxide deposition from inclusion complexes: Decomposition mechanism, structure, and properties

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dc.contributor.author Papadopoulos, ND en
dc.contributor.author Karayianni, HS en
dc.contributor.author Tsakiridis, PE en
dc.contributor.author Perraki, M en
dc.contributor.author Sarantopoulou, E en
dc.contributor.author Hristoforou, E en
dc.date.accessioned 2014-03-01T01:36:18Z
dc.date.available 2014-03-01T01:36:18Z
dc.date.issued 2011 en
dc.identifier.issn 0013-4651 en
dc.identifier.uri https://dspace.lib.ntua.gr/xmlui/handle/123456789/21283
dc.subject.classification Electrochemistry en
dc.subject.classification Materials Science, Coatings & Films en
dc.subject.other Abnormal behavior en
dc.subject.other Cobalt oxide films en
dc.subject.other Cobalt oxides en
dc.subject.other Decomposition mechanism en
dc.subject.other In-plane magnetization en
dc.subject.other Inclusion complex en
dc.subject.other MOCVD en
dc.subject.other Nano-crystalline structures en
dc.subject.other Novel precursors en
dc.subject.other Semiconducting behavior en
dc.subject.other Cobalt en
dc.subject.other Cobalt compounds en
dc.subject.other Decomposition en
dc.subject.other Electric properties en
dc.subject.other Magnetic properties en
dc.subject.other Metallorganic chemical vapor deposition en
dc.subject.other Organometallics en
dc.subject.other Semiconducting films en
dc.subject.other Silicides en
dc.subject.other Oxide films en
dc.title MOCVD cobalt oxide deposition from inclusion complexes: Decomposition mechanism, structure, and properties en
heal.type journalArticle en
heal.identifier.primary 10.1149/1.3509698 en
heal.identifier.secondary http://dx.doi.org/10.1149/1.3509698 en
heal.language English en
heal.publicationDate 2011 en
heal.abstract A novel precursor based on the inclusion complex of beta-cyclodextrin with CoI2 is proposed for the deposition of cobalt oxide films by metallorganic chemical vapor deposition (MOCVD). Deposition is viable through an abnormal behavior of the inclusion molecules during heating. A decomposition mechanism based on experimental results is proposed, while the films are examined in terms of microstructure, electrical, and magnetic properties. A uniform, nanocrystalline structure of Co3O4 was revealed, along with impurities of silicide phases. The films presented a semiconducting behavior and minor in-plane magnetization. (c) 2010 The Electrochemical Society. en
heal.publisher ELECTROCHEMICAL SOC INC en
heal.journalName Journal of the Electrochemical Society en
dc.identifier.doi 10.1149/1.3509698 en
dc.identifier.isi ISI:000284697900056 en
dc.identifier.volume 158 en
dc.identifier.issue 1 en
dc.identifier.spage P5 en
dc.identifier.epage P13 en


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