EFFICIENT, ONE-POT SYNTHESIS OF SUSPENSION CROSS-LINKED SULFONATED POLYSTYRENE VIA A FRIEDEL CRAFTS REACTION

THEODOROPOULOS, AG; BOURANIS, DL; VALKANAS, GN

dc.contributor.author	THEODOROPOULOS, AG	en
dc.contributor.author	BOURANIS, DL	en
dc.contributor.author	VALKANAS, GN	en
dc.date.accessioned	2014-03-01T01:41:24Z
dc.date.available	2014-03-01T01:41:24Z
dc.date.issued	1992	en
dc.identifier.issn	0021-8995	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/23484
dc.subject.classification	Polymer Science	en
dc.subject.other	PHYSICAL CHARACTERIZATION	en
dc.subject.other	PARTICLES	en
dc.subject.other	PRODUCTS	en
dc.subject.other	NETWORKS	en
dc.title	EFFICIENT, ONE-POT SYNTHESIS OF SUSPENSION CROSS-LINKED SULFONATED POLYSTYRENE VIA A FRIEDEL CRAFTS REACTION	en
heal.type	journalArticle	en
heal.language	English	en
heal.publicationDate	1992	en
heal.abstract	A suspension technique leading to macronet ionic resins is described based on a single reactor process. The procedures demonstrate sulfuric acid as a polar suspending medium that can act as a sulfonating agent, a Friedel-Crafts catalyst, and a crosslinking agent. The sulfonation reaction was finally completed using sulfuric acid excess, or oleum 65%. High yields were obtained for the crosslinking and the sulfonation reaction, while the final products were characterized by using ion-exchange capacity measurements, U.V. spectra, and determination of the degree of crosslinking. The number average molecular weight between crosslinks and the ion-exchange capacity H+ --> Na+ of the resins was decreasing by increasing the nominal crosslinking ratio.	en
heal.publisher	JOHN WILEY & SONS INC	en
heal.journalName	JOURNAL OF APPLIED POLYMER SCIENCE	en
dc.identifier.isi	ISI:A1992JT54100017	en
dc.identifier.volume	46	en
dc.identifier.issue	8	en
dc.identifier.spage	1461	en
dc.identifier.epage	1465	en