Application of the LCVM model to systems containing organic compounds and supercritical carbon dioxide

Yakoumis, IV; Vlachos, K; Kontogeorgis, GM; Coutsikos, P; Kalospiros, NS; Tassios, D; Kolisis, FN

dc.contributor.author	Yakoumis, IV	en
dc.contributor.author	Vlachos, K	en
dc.contributor.author	Kontogeorgis, GM	en
dc.contributor.author	Coutsikos, P	en
dc.contributor.author	Kalospiros, NS	en
dc.contributor.author	Tassios, D	en
dc.contributor.author	Kolisis, FN	en
dc.date.accessioned	2014-03-01T01:44:39Z
dc.date.available	2014-03-01T01:44:39Z
dc.date.issued	1996	en
dc.identifier.issn	08968446	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/24441
dc.relation.uri	http://www.scopus.com/inward/record.url?eid=2-s2.0-0002326887&partnerID=40&md5=31a5c135a6120b1b61890a60c4266858	en
dc.subject	Biotechnology	en
dc.subject	Carbon dioxide	en
dc.subject	EOS/GE model	en
dc.subject	Equation of state	en
dc.subject	Solubility	en
dc.subject	Vapor-liquid equilibria	en
dc.title	Application of the LCVM model to systems containing organic compounds and supercritical carbon dioxide	en
heal.type	journalArticle	en
heal.publicationDate	1996	en
heal.abstract	A recently developed equation of state-excess Gibbs free energy (EOS/GE) model with the LCVM (linear combination of Vidai and Michelsen) mixing rule, capable of successful VLE prediction in asymmetric systems is applied to the prediction of solubilities of alkenes, ethers, acids, alcohols, and esters in supercritical carbon dioxide. Considering the experimental uncertainties, excellent correlation of binary data and satisfactory prediction of ternary and multicomponent equilibria are obtained in most cases over a wide range of temperature, pressure, and system asymmetry. These promising results render the LCVM model a useful tool for the preliminary design of processes involving mixtures with organic compounds and supercritical carbon dioxide.	en
heal.journalName	Journal of Supercritical Fluids	en
dc.identifier.volume	9	en
dc.identifier.issue	2	en
dc.identifier.spage	88	en
dc.identifier.epage	98	en