Application of the LCVM model to systems containing organic compounds and supercritical carbon dioxide

Yakoumis, IV; Vlachos, K; Kontogeorgis, GM; Coutsikos, P; Kalospiros, NS; Tassios, D

dc.contributor.author	Yakoumis, IV	en
dc.contributor.author	Vlachos, K	en
dc.contributor.author	Kontogeorgis, GM	en
dc.contributor.author	Coutsikos, P	en
dc.contributor.author	Kalospiros, NS	en
dc.contributor.author	Tassios, D	en
dc.date.accessioned	2014-03-01T01:45:04Z
dc.date.available	2014-03-01T01:45:04Z
dc.date.issued	1996	en
dc.identifier.issn	0896-8446	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/24539
dc.subject	equation of state	en
dc.subject	EOS/G(E) model	en
dc.subject	solubility	en
dc.subject	vapor-liquid equilibria	en
dc.subject	carbon dioxide	en
dc.subject	biotechnology	en
dc.subject.classification	Chemistry, Physical	en
dc.subject.classification	Engineering, Chemical	en
dc.subject.other	VAPOR-LIQUID-EQUILIBRIA	en
dc.subject.other	FLUID-PHASE-EQUILIBRIUM	en
dc.subject.other	VIDAL MIXING RULE	en
dc.subject.other	BINARY-MIXTURES	en
dc.subject.other	HIGH-PRESSURES	en
dc.subject.other	AROMATIC-HYDROCARBONS	en
dc.subject.other	TERNARY MIXTURES	en
dc.subject.other	CUBIC EQUATIONS	en
dc.subject.other	EOS/G(E) MODELS	en
dc.subject.other	METHYL BENZOATE	en
dc.title	Application of the LCVM model to systems containing organic compounds and supercritical carbon dioxide	en
heal.type	journalArticle	en
heal.language	English	en
heal.publicationDate	1996	en
heal.abstract	A recently developed equation of state-excess Gibbs free energy (EOS/G(E)) model with the LCVM (linear combination of Vidal and Michelsen) mixing rule, capable of successful VLE prediction in asymmetric systems is applied to the prediction of solubilities of alkenes, ethers, acids, alcohols, and esters in supercritical carbon dioxide. Considering the experimental uncertainties, excellent correlation of binary data and satisfactory prediction of ternary and multicomponent equilibria are obtained in most cases over a wide range of temperature, pressure, and system asymmetry. These promising results render the LCVM model a useful tool for the preliminary design of processes involving mixtures with organic compounds and supercritical carbon dioxide.	en
heal.publisher	PRA PRESS	en
heal.journalName	JOURNAL OF SUPERCRITICAL FLUIDS	en
dc.identifier.isi	ISI:A1996UZ73700004	en
dc.identifier.volume	9	en
dc.identifier.issue	2	en
dc.identifier.spage	88	en
dc.identifier.epage	98	en