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The electric dipole approximation and the calculation of free-free transition matrix elements in multiphoton processes

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dc.contributor.author Mercouris, Th en
dc.contributor.author Komninos, Y en
dc.contributor.author Dionissopoulou, S en
dc.contributor.author Nicolaides, CA en
dc.date.accessioned 2014-03-01T01:46:15Z
dc.date.available 2014-03-01T01:46:15Z
dc.date.issued 1997 en
dc.identifier.issn 09534075 en
dc.identifier.uri https://dspace.lib.ntua.gr/xmlui/handle/123456789/24874
dc.title The electric dipole approximation and the calculation of free-free transition matrix elements in multiphoton processes en
heal.type journalArticle en
heal.identifier.primary 10.1088/0953-4075/30/9/014 en
heal.identifier.secondary http://dx.doi.org/10.1088/0953-4075/30/9/014 en
heal.publicationDate 1997 en
heal.abstract In view of the arguments put forward by van Enk et al, we discuss aspects of the theory of atom-laser field interactions as they relate to the calculation of properties for which free-free transitions play a significant role. Our conclusion is that: (i) according to the standard definition of the electric dipole approximation, which is what has been employed until now in all non-perturbative calculations of multiphoton processes, the on-energy shell singularity for the length and velocity gauges is real when the one-electron continuum is represented rigorously by energy-normalized scattering functions. On the other hand, the acceleration gauge does not give rise to this singularity. (ii) When the full coupling operator A(r) · p + 1/2 A2(r) rather than A(r) · p is used, the singularity persists for the electric dipole as well as for the higher multipoles. (iii) The use of box-normalized basis sets only leads to a model space whereby even repeated (and computationally expensive) calculations with increasing box size lack intrinsic rigour and the certainty that convergence implies accuracy. en
heal.journalName Journal of Physics B: Atomic, Molecular and Optical Physics en
dc.identifier.doi 10.1088/0953-4075/30/9/014 en
dc.identifier.volume 30 en
dc.identifier.issue 9 en
dc.identifier.spage 2133 en
dc.identifier.epage 2141 en


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