On the 4f25d → 4f3 interconfigurational transitions of Nd3+ ions in K2YF5 and LiYF4 crystal hosts

Kollia, Z; Sarantopoulou, E; Cefalas, AC; Naumov, AK; Semashko, VV; Abdulsabirov, RY; Korableva, SL

dc.contributor.author	Kollia, Z	en
dc.contributor.author	Sarantopoulou, E	en
dc.contributor.author	Cefalas, AC	en
dc.contributor.author	Naumov, AK	en
dc.contributor.author	Semashko, VV	en
dc.contributor.author	Abdulsabirov, RY	en
dc.contributor.author	Korableva, SL	en
dc.date.accessioned	2014-03-01T01:47:25Z
dc.date.available	2014-03-01T01:47:25Z
dc.date.issued	1998	en
dc.identifier.issn	00304018	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/25204
dc.relation.uri	http://www.scopus.com/inward/record.url?eid=2-s2.0-0032045363&partnerID=40&md5=6331d65a615a751aa7d2b22e49ec50f0	en
dc.subject	Dielectric crystals	en
dc.subject	Laser induced fluorescence	en
dc.subject	Trivalent rare earth ions	en
dc.subject	Vacuum ultraviolet	en
dc.title	On the 4f25d → 4f3 interconfigurational transitions of Nd3+ ions in K2YF5 and LiYF4 crystal hosts	en
heal.type	journalArticle	en
heal.publicationDate	1998	en
heal.abstract	The Laser Induced Fluorescence (LIF) spectrum of K2YF5:Nd3+ (PFYK:Nd) and LiYF4:Nd3+ (YLF:Nd) single crystals, pumped by the fluorine F2 pulsed discharge molecular laser at 157.6 nm, was obtained in the Vacuum Ultraviolet (VUV) region of the spectrum. The fluorescence peaks were assigned to the 4f25d → 4f3 dipole allowed transitions of the Nd3+ ion. The 180 nm band of the LIF spectrum from the crystals indicates that the 4f25d → 4f3 dipole transitions originate from the low Stark components of the4K11/2 level of the 4f25d configuration. The absorption spectrum of the crystal samples in the VUV was obtained as well and spectroscopic assignment of the levels of the 4f25d configuration was made. The electric crystal field splits all the levels of single and mixed configuration. The energy of the Stark components of the 4f25d configuration in YLF:Nd was shifted by few hundred cm-1 relative to that of PFYK:Nd. We observed eleven and nine dipole transitions, between the4I9/2 ground level of the 4f3 configuration and the Stark components of the levels of the 4f25d configuration of the Nd3+ ion, in YLF and PFYK crystal hosts, respectively. © 1998 Elsevier Science B.V.	en
heal.journalName	Optics Communications	en
dc.identifier.volume	149	en
dc.identifier.issue	4-6	en
dc.identifier.spage	386	en
dc.identifier.epage	392	en