dc.contributor.author |
Gourbatsis, S |
en |
dc.contributor.author |
Hadjiliadis, N |
en |
dc.contributor.author |
Perlepes, SP |
en |
dc.contributor.author |
Garoufis, A |
en |
dc.contributor.author |
Butler, IS |
en |
dc.date.accessioned |
2014-03-01T01:47:29Z |
|
dc.date.available |
2014-03-01T01:47:29Z |
|
dc.date.issued |
1998 |
en |
dc.identifier.issn |
03404285 |
en |
dc.identifier.uri |
https://dspace.lib.ntua.gr/xmlui/handle/123456789/25227 |
|
dc.relation.uri |
http://www.scopus.com/inward/record.url?eid=2-s2.0-33847243871&partnerID=40&md5=6339edf60790cbb4798b91bca3be8b67 |
en |
dc.title |
Structural and spectroscopic characterization of a cationic aquanitrato copper(II) complex with the tetradentate Schiff-base ligand N,N′-bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine |
en |
heal.type |
journalArticle |
en |
heal.publicationDate |
1998 |
en |
heal.abstract |
Cu(NO3)2 · 3H2O reacts with 1 equiv. of the tetradentate Schiff base N,N′-bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine (LA) in refluxing acetone to yield the [CuLA(ONO2)(H2O)](NO3) complex in ca. 80% yield. The structure of this salt has been determined by single-crystal X-ray crystallography. The copper is six-coordinated with the LA ligand in the equatorial plane and weakly bonded aqua and nitrato ligands above and below this plane. The complex cation is hydrogenbonded to the nitrate counter-ion. The complex was also characterized by elemental analyses, molar conductivity, room-temperature magnetic susceptibility and spectroscopic (i.r., far-i.r., u.v.-vis, e.s.r.) studies. The data are discussed in terms of the nature of bonding and the known structure. |
en |
heal.journalName |
Transition Metal Chemistry |
en |
dc.identifier.volume |
23 |
en |
dc.identifier.issue |
5 |
en |
dc.identifier.spage |
599 |
en |
dc.identifier.epage |
604 |
en |