Structural and spectroscopic characterization of a cationic aquanitrato copper(II) complex with the tetradentate Schiff-base ligand N,N′-bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine

Gourbatsis, S; Hadjiliadis, N; Perlepes, SP; Garoufis, A; Butler, IS

dc.contributor.author	Gourbatsis, S	en
dc.contributor.author	Hadjiliadis, N	en
dc.contributor.author	Perlepes, SP	en
dc.contributor.author	Garoufis, A	en
dc.contributor.author	Butler, IS	en
dc.date.accessioned	2014-03-01T01:47:29Z
dc.date.available	2014-03-01T01:47:29Z
dc.date.issued	1998	en
dc.identifier.issn	03404285	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/25227
dc.relation.uri	http://www.scopus.com/inward/record.url?eid=2-s2.0-33847243871&partnerID=40&md5=6339edf60790cbb4798b91bca3be8b67	en
dc.title	Structural and spectroscopic characterization of a cationic aquanitrato copper(II) complex with the tetradentate Schiff-base ligand N,N′-bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine	en
heal.type	journalArticle	en
heal.publicationDate	1998	en
heal.abstract	Cu(NO3)2 · 3H2O reacts with 1 equiv. of the tetradentate Schiff base N,N′-bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine (LA) in refluxing acetone to yield the [CuLA(ONO2)(H2O)](NO3) complex in ca. 80% yield. The structure of this salt has been determined by single-crystal X-ray crystallography. The copper is six-coordinated with the LA ligand in the equatorial plane and weakly bonded aqua and nitrato ligands above and below this plane. The complex cation is hydrogenbonded to the nitrate counter-ion. The complex was also characterized by elemental analyses, molar conductivity, room-temperature magnetic susceptibility and spectroscopic (i.r., far-i.r., u.v.-vis, e.s.r.) studies. The data are discussed in terms of the nature of bonding and the known structure.	en
heal.journalName	Transition Metal Chemistry	en
dc.identifier.volume	23	en
dc.identifier.issue	5	en
dc.identifier.spage	599	en
dc.identifier.epage	604	en