Copper(II), cobalt(II), nickel(II) and zinc(II) complexes containing the enolate of N-acetyl-3-butanoyltetramic acid (Habta) and its phenylhydrazone derivative analogues. Crystal structure of [Cu(abta)(2)(py)(2)]center dot 2H(2)O

Gavrielatos, E; Mitsos, C; Athanasellis, G; Heaton, BT; Steiner, A; Bickley, JF; Igglessi-Markopoulou, O; Markopoulos, J

dc.contributor.author	Gavrielatos, E	en
dc.contributor.author	Mitsos, C	en
dc.contributor.author	Athanasellis, G	en
dc.contributor.author	Heaton, BT	en
dc.contributor.author	Steiner, A	en
dc.contributor.author	Bickley, JF	en
dc.contributor.author	Igglessi-Markopoulou, O	en
dc.contributor.author	Markopoulos, J	en
dc.date.accessioned	2014-03-01T01:51:05Z
dc.date.available	2014-03-01T01:51:05Z
dc.date.issued	2001	en
dc.identifier.issn	1472-7773	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/26227
dc.subject.classification	Chemistry, Inorganic & Nuclear	en
dc.subject.other	TRANSITION-METAL COMPLEXES	en
dc.subject.other	COORDINATION	en
dc.subject.other	IONS	en
dc.title	Copper(II), cobalt(II), nickel(II) and zinc(II) complexes containing the enolate of N-acetyl-3-butanoyltetramic acid (Habta) and its phenylhydrazone derivative analogues. Crystal structure of [Cu(abta)(2)(py)(2)]center dot 2H(2)O	en
heal.type	journalArticle	en
heal.language	English	en
heal.publicationDate	2001	en
heal.abstract	Reaction of N-acetyl-3-butanoyltetramic acid (N-acetyl-3-butanoyl-4-hydroxypyrrolidin-2-one) (Habta) with M(CH3CO2)(2). xH(2)O (x=1, 2 or 4; M=Cu-II, Co-II or Ni-II) in a 1:1 ratio gave M(CH3CO2)(abta). yH(2)O 1, 3, 5 and in 1:2 ratio M(abta)(2).y'H2O 2, 4, 6. A new ligand, the phenylhydrazone of Habta (HPhabta), has been prepared and reacts with M(CH3CO2)(2). xH(2)O (x=2 or 4; M=Cu-II or Co-II) in a 1:1 and 1:2 ratio to give the analogous complexes M(CH3CO2)(Phabta). zH(2)O 9, 11 and M(Phabta)(2).z'H2O 10 respectively. The solid state structure of [Cu(abta)(2)(py)(2)]. 2H(2)O 2a has been determined by single crystal X-ray diffraction. It shows that copper adopts a slightly distorted octahedral co-ordination geometry with the abta enolate ligand adopting an O,O' mode of co-ordination via the functionalities associated with C-4 and the acyl group at C-3 in the pyrrolidine ring. The reaction of Habta with Zn(CH3CO2)(2). 2H(2)O in 1:1 ratio gives a complex 7 with a deacetylated ligand whereas, with 1:2 ratio, Zn(abta)(2). 2H(2)O 8 is obtained. In contrast the reaction of HPhabta with Zn(CH3CO2)(2). 2H(2)O, irrespective of the metal to ligand ratio, gives Zn(CH3CO2)(Phbta). 2H(2)O 12 containing the deacetylated ligand.	en
heal.publisher	ROYAL SOC CHEMISTRY	en
heal.journalName	JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS	en
dc.identifier.isi	ISI:000167499500024	en
dc.identifier.issue	5	en
dc.identifier.spage	639	en
dc.identifier.epage	644	en