A novel coordination mode of the 1-hydroxybenzotriazolate (btaO−) ligand: preparation, X-ray crystal structure and spectroscopic characterizationof the trinuclear complex [Ni3(btaO)6(NH3)6]

Diamantopoulou, E; Perlepes, S; Raptis, D; Raptopoulou, C

dc.contributor.author	Diamantopoulou, E	en
dc.contributor.author	Perlepes, S	en
dc.contributor.author	Raptis, D	en
dc.contributor.author	Raptopoulou, C	en
dc.date.accessioned	2014-03-01T01:51:27Z
dc.date.available	2014-03-01T01:51:27Z
dc.date.issued	2002	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/26294
dc.subject	Field Study	en
dc.subject	Hydrogen Bond	en
dc.subject	Ligand Binding	en
dc.subject	Magnetic Moment	en
dc.subject	Metal Ion	en
dc.subject	Room Temperature	en
dc.subject	Single Crystal	en
dc.subject	Structural Similarity	en
dc.subject	X-ray Crystal Structure	en
dc.subject	X-ray Crystallography	en
dc.title	A novel coordination mode of the 1-hydroxybenzotriazolate (btaO−) ligand: preparation, X-ray crystal structure and spectroscopic characterizationof the trinuclear complex [Ni3(btaO)6(NH3)6]	en
heal.type	journalArticle	en
heal.identifier.primary	10.1023/A:1015062300672	en
heal.identifier.secondary	http://dx.doi.org/10.1023/A:1015062300672	en
heal.publicationDate	2002	en
heal.abstract	Reaction of Ni(NO3)2 · 6H2O with 1-hydroxybenzotriazole (btaOH) in DMF/aqueous NH3 and layering of the resulting solution with MeCN yields the complex [Ni3(btaO)6(NH3)6] · 0.47DMF · 0.75MeCN · 1.58H2O, (ca. 80% yield), the structure of which has been determined by single-crystal X-ray crystallography. The asymmetric unit contains two, structurally similar, trinuclear molecules. The six-coordinate NiII atom is linked to each	en
dc.identifier.doi	10.1023/A:1015062300672	en