heal.abstract |
For the understanding of irreversibility at the quantum level, the formation and decay of transient (unstable) states play a fundamental role. If the system is treated within Hermitian quantum mechanics, the resulting energy distribution of the resonance state, whose Fourier transform yields the time-dependent probability of decay, P(t), is real. The physical constraint of the lower bound in the energy spectrum introduces "memory," and causes nonexponential decay (NED) to set in after t>tau, where tau is the lifetime defined by exponential decay. The closer to threshold the decaying state is, the earlier NED appears. Apart from the constraint of Egreater than or equal to0, the constraint of tgreater than or equal to0 must be accounted for at the same time. It results from the discontinuity at t=0 of the solution of the time-dependent Schrodinger equation, which breaks the unitarity associated with the S matrix and gives rise to a complex energy distribution, as a manifestation of the non-Hermitian property of the decaying states. For a narrow isolated resonance state, for which the self-energy is essentially energy-independent, analytic results for P-NED(t) obtained from semiclassical path-integral calculations agree with the quantum-mechanical ones when both physical constraints E>0 and t>0 are taken into account. As an example of the difference in the magnitude of the P-NED(t) when using a real and a complex energy distribution, application is made to the decay of the unstable He-2(2+) (1)Sigma(g)(+) ground molecular state. |
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