heal.abstract |
In the present study, the reductive behavior of nickeliferous dust from rotary kilns, during Greek laterite treatment in ferronickel production is investigated. The study concerns dust of various origins, i.e. washing towers, electrostatic filters and polycyclones. Laboratory made pellets from these dusts were also examined. Reducibility was studied in the temperature range of 700°C to 850°C in a laboratory tube furnace. Experimental results showed that the reduction degree reaches maximum values of 28% and 26% percentage for dusts and pellets respectively within the first twenty minutes of the process, and then reaction tends to equilibrium for all cases examined. The rate of reduction increases significantly during the first ten minutes of reaction and then it becomes lower until it diminishes to zero after twenty minutes of roasting. Temperature favors the reduction process, the reduction percentage being increased as a function of temperature up to about 800°C. Rates and reduction degrees are higher for the dusts than for the corresponding pellets, for all experimental conditions examined. Kinetic analysis of the results showed that at low temperature values the mixed kinetic model verifies the experimental results of dust and pellet samples. At higher temperatures (800°C and 850°C), diffusion becomes the rate determining step. The change in the controlling mechanism is attributed to the formation of silicate compounds around the grains as temperature rises. The calculated activation energy values verify the above mentioned results. |
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