A convenient one-pot synthesis of α-chloro-α- chlorosulfenylimidoyl chlorides via an abnormal reaction of excess thionyl chloride on secondary amides

Tsolomiti, G; Tsolomiti, K; Tsolomitis, A

dc.contributor.author	Tsolomiti, G	en
dc.contributor.author	Tsolomiti, K	en
dc.contributor.author	Tsolomitis, A	en
dc.date.accessioned	2014-03-01T01:56:16Z
dc.date.available	2014-03-01T01:56:16Z
dc.date.issued	2007	en
dc.identifier.issn	07930283	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/28029
dc.relation.uri	http://www.scopus.com/inward/record.url?eid=2-s2.0-34547617711&partnerID=40&md5=896aea14c2ca0fec88424bdaf0bb69fc	en
dc.title	A convenient one-pot synthesis of α-chloro-α- chlorosulfenylimidoyl chlorides via an abnormal reaction of excess thionyl chloride on secondary amides	en
heal.type	journalArticle	en
heal.publicationDate	2007	en
heal.abstract	A one-pot procedure is described for the preparation of α-chloro-α-chlorosulfenyl-imidoyl chlorides from the abnormal reaction of thionyl chloride on some secondary amides. The results are consistent only with excess thionyl chloride oxidation proceeding exclusively at the α-methylene to the amide carbonyl function. The functionality of these products plus the efficiency of the method and the good yields, (up to 75%), could offer a useful tool for synthetic purposes.	en
heal.journalName	Heterocyclic Communications	en
dc.identifier.volume	13	en
dc.identifier.issue	2-3	en
dc.identifier.spage	173	en
dc.identifier.epage	176	en