A convenient one-pot synthesis of alpha-chloro-alpha-chlorosulfenyl-imidoyl chlorides via an abnormal reaction of excess thionyl chloride on secondary amides

Tsolomiti, G; Tsolomiti, K; Tsolomitis, A

dc.contributor.author	Tsolomiti, G	en
dc.contributor.author	Tsolomiti, K	en
dc.contributor.author	Tsolomitis, A	en
dc.date.accessioned	2014-03-01T01:56:26Z
dc.date.available	2014-03-01T01:56:26Z
dc.date.issued	2007	en
dc.identifier.issn	0793-0283	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/28096
dc.subject.classification	Chemistry, Organic	en
dc.subject.other	OXIDATIONS	en
dc.subject.other	KETONES	en
dc.subject.other	KETIMINES	en
dc.subject.other	MECHANISM	en
dc.subject.other	ACIDS	en
dc.title	A convenient one-pot synthesis of alpha-chloro-alpha-chlorosulfenyl-imidoyl chlorides via an abnormal reaction of excess thionyl chloride on secondary amides	en
heal.type	journalArticle	en
heal.language	English	en
heal.publicationDate	2007	en
heal.abstract	A one-pot procedure is described for the preparation of alpha-chloro-alpha-chlorosulfenyl-imidoyl chlorides from the abnormal reaction of thionyl chloride on some secondary amides. The results are consistent only with excess thionyl chloride oxidation proceeding exclusively at the alpha-methylene to the amide carbonyl function. The functionality of these products plus the efficiency of the method and the good yields, (up to 75%), could offer a useful tool for synthetic purposes.	en
heal.publisher	FREUND PUBLISHING HOUSE LTD	en
heal.journalName	HETEROCYCLIC COMMUNICATIONS	en
dc.identifier.isi	ISI:000248402700014	en
dc.identifier.volume	13	en
dc.identifier.issue	2-3	en
dc.identifier.spage	173	en
dc.identifier.epage	176	en