Synthesis and crystal structure characterization of zinc (II) tetronic acid complexes

Markopoulos, J; Prousis, KC; Athanasellis, G; Stefanou, V; Matiadis, D; Kokalari, E; Igglessi-Markopoulou, O; McKee, V

dc.contributor.author	Markopoulos, J	en
dc.contributor.author	Prousis, KC	en
dc.contributor.author	Athanasellis, G	en
dc.contributor.author	Stefanou, V	en
dc.contributor.author	Matiadis, D	en
dc.contributor.author	Kokalari, E	en
dc.contributor.author	Igglessi-Markopoulou, O	en
dc.contributor.author	McKee, V	en
dc.date.accessioned	2014-03-01T01:59:55Z
dc.date.available	2014-03-01T01:59:55Z
dc.date.issued	2010	en
dc.identifier.issn	15653633	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/29057
dc.title	Synthesis and crystal structure characterization of zinc (II) tetronic acid complexes	en
heal.type	journalArticle	en
heal.identifier.primary	10.1155/2010/651652	en
heal.identifier.secondary	http://dx.doi.org/10.1155/2010/651652	en
heal.identifier.secondary	651652	en
heal.publicationDate	2010	en
heal.abstract	The synthesis and characterization of two new tetronic acid zinc (II) complexes of the empirical formulae [Zn (L-H)2(H2O) 2] (1) and [Zn (L-H)2(H2O)(MeOH)]H2O (2) found within the same crystal are reported. The zinc ions bind through alkoxide and carbonyl groups of the ligand 3-methoxycarbonyl-5-phenyl tetronic acid (LH) as indicated by 1H NMR and X-ray crystallographic studies. These complexes promote intra- and intermolecular interactions, such as hydrogen bonding and stacking, giving place to the formation of molecular aggregates. Copyright © 2010 K. C. Prousis et al.	en
heal.journalName	Bioinorganic Chemistry and Applications	en
dc.identifier.doi	10.1155/2010/651652	en
dc.identifier.volume	2010	en