Lipase-mediated epoxidation of α-pinene

Skouridou, V; Stamatis, H; Kolisis, FN

dc.contributor.author	Skouridou, V	en
dc.contributor.author	Stamatis, H	en
dc.contributor.author	Kolisis, FN	en
dc.date.accessioned	2014-03-01T02:42:17Z
dc.date.available	2014-03-01T02:42:17Z
dc.date.issued	2003	en
dc.identifier.issn	1381-1177	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/30909
dc.subject	α-pinene	en
dc.subject	Candida antarctica	en
dc.subject	Octanoic acid	en
dc.subject.classification	Biochemistry & Molecular Biology	en
dc.subject.classification	Chemistry, Physical	en
dc.subject.other	Enzyme immobilization	en
dc.subject.other	Hydrogen peroxide	en
dc.subject.other	Synthesis (chemical)	en
dc.subject.other	Toluene	en
dc.subject.other	Epoxidation	en
dc.subject.other	Enzymes	en
dc.subject.other	hydrogen peroxide	en
dc.subject.other	octanoic acid derivative	en
dc.subject.other	pinene	en
dc.subject.other	toluene	en
dc.subject.other	triacylglycerol lipase	en
dc.subject.other	water	en
dc.subject.other	Candida antarctica	en
dc.subject.other	conference paper	en
dc.subject.other	environmental temperature	en
dc.subject.other	enzyme immobilization	en
dc.subject.other	epoxidation	en
dc.subject.other	fungal strain	en
dc.subject.other	nonhuman	en
dc.subject.other	synthesis	en
dc.subject.other	Candida antarctica	en
dc.title	Lipase-mediated epoxidation of α-pinene	en
heal.type	conferenceItem	en
heal.identifier.primary	10.1016/S1381-1177(02)00141-8	en
heal.identifier.secondary	http://dx.doi.org/10.1016/S1381-1177(02)00141-8	en
heal.language	English	en
heal.publicationDate	2003	en
heal.abstract	This work describes the lipase-mediated synthesis of alpha-pinene oxide at ambient temperature. The immobilized lipase from Candida antarctica (Novozyme 435) is used to generate peroxyoctanoic acid directly from octanoic acid and hydrogen peroxide. The peroxy acid formed is then applied I for in situ oxidation of alpha-pinene. High conversion of alpha-pinene to alpha-pinene oxide (approximately 70%) was achieved when using a two-phase system of toluene and water. Various parameters affecting the conversion of alpha-pinene to alpha-pinene oxide were studied. (C) 2002 Elsevier Science B.V. All rights reserved.	en
heal.publisher	ELSEVIER SCIENCE BV	en
heal.journalName	Journal of Molecular Catalysis B: Enzymatic	en
dc.identifier.doi	10.1016/S1381-1177(02)00141-8	en
dc.identifier.isi	ISI:000180290000016	en
dc.identifier.volume	21	en
dc.identifier.issue	1-2	en
dc.identifier.spage	67	en
dc.identifier.epage	69	en