Polyoxometallates as effective photocatalysts in water purification from pesticides

Gkika, E; Kormali, P; Antonaraki, S; Dimoticali, D; Papaconstantinou, E; Hiskia, A

dc.contributor.author	Gkika, E	en
dc.contributor.author	Kormali, P	en
dc.contributor.author	Antonaraki, S	en
dc.contributor.author	Dimoticali, D	en
dc.contributor.author	Papaconstantinou, E	en
dc.contributor.author	Hiskia, A	en
dc.date.accessioned	2014-03-01T02:49:54Z
dc.date.available	2014-03-01T02:49:54Z
dc.date.issued	2004	en
dc.identifier.issn	1110662X	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/34766
dc.relation.uri	http://www.scopus.com/inward/record.url?eid=2-s2.0-24044475263&partnerID=40&md5=e59edcc9aa393f4687d7d166849cb22e	en
dc.title	Polyoxometallates as effective photocatalysts in water purification from pesticides	en
heal.type	conferenceItem	en
heal.publicationDate	2004	en
heal.abstract	Polyoxometallates (POM), i.e., metal oxide clusters of mainly tungsten are effective homogeneous photocatalysts for the mineralization of organic pollutants. POM are, at least, as effective as the well studied TiO2. OH.radicals formed by the reaction of the photo-excited polyoxometallates with H2O, appear to play a key role in the process. In this study, the photocatalytic activity of POM have been tested on some diversified pesticides of interest such as lindane, bentazone and fenitrothion to determine the feasibility of decontamination of aqueous solutions from these pollutants. The results show that aqueous solutions containing the above pesticides, upon photolysis in the presence of polyoxotungstates undergo effective degradation to CO2, H2O and the corresponding inorganic anions. The intermediates identified give rise to complicated degradation mechanisms prior to mineralization. The characteristic reactions that take place consist of hydroxylation, H-abstraction, dehalogenation, denitration, desulfurization, breaking of the C-C bond etc.	en
heal.journalName	International Journal of Photoenergy	en
dc.identifier.volume	6	en
dc.identifier.issue	4	en
dc.identifier.spage	227	en
dc.identifier.epage	231	en