heal.abstract |
The objective of the present thesis is the study of the corrosion behavior of HSLA S460
structural steel, its homogeneous weldment S460-S460 and its weldment with conventional
steel AH36-S460 and the comparison with the conventional parent metal AH36 and
AH36-AH36 weldment. This study investigates the corrosion performance of this steel as an
alternative of conventional steel AH36 for applications on the ship.
Electrochemical techniques were employed, applying DC and AC techniques, along with
study of the microstructure and micro-hardness. In particular, Linear Polarization,
Potentiodynamic polarization, Cyclic polarization and Electrochemical Impedance
Spectroscopy electrochemical techniques were applied.
The potentiodynamic polarization of the specimens proved that the phenomenon is
determined by the O2 diffusion in the 3.5% NaCl solution, which is obvious in the cathodic
polarization, i.e concentration polarization. Thus, it is the O2 concentration of the solution that
determines the corrosion rate of the specimen. The anodic polarization is characterized by an
increase of current density with increasing potential in the anodic region, indicating active
corrosion behavior without passivation.
The corrosion parameters show that S460 presents very similar corrosion behavior with
AH36 with no significant difference. Both metals present similar microstructure, as well as their
weldments. The icorr values and the consequent corrosion rates are quite similar for the parent
metals and the welds. However, in EIS technique S460-S460 weld is more corrosion resistant;
this difference can be explained by the difference of the perturbation applied on the specimen,
with EIS.
The aforementioned results prove that concerning the corrosion performance, S460 can be
introduced as an alternate material instead of or along with AH36. Whereas, it is useful to study
the corrosion in combination with fatigue performance. |
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