heal.abstract |
In this thesis, the environmental impacts of three alternative scenarios for the valorization of
orange waste were investigated and compared to the conventional waste management method
currently applied by Greek industries, which involves the disposal of solid waste in sanitary
landfills and the discharge of liquid waste in urban wastewater treatment plants. To assess their
environmental impacts, a Life Cycle Assessment (LCA) was conducted using the ReCiPe
methodology in GaBi software, where input and output values of raw materials, as well as
electricity and thermal energy consumption, were introduced. The LCA inventory values in GaBi
for solid waste management were derived from models developed using SuperPro Designer
process simulation software, based on experimental results from the literature, while the data for
the wastewater management were obtained from bibliographic references.
Scenario 1 involves the hydrodistillation of solid waste for the recovery of essential oils, followed
by the anaerobic digestion of the sludge, resulting in the production of biogas and fertilizer, while
the wastewater undergoes membrane treatment and chlorination. In Scenario 2, the solid waste
is subjected to steam explosion treatment, which facilitates the separation of essential oils,
followed by pectin precipitation and separation using ethanol and, finally, anaerobic digestion.
The wastewater is treated in an aeration tank and chlorinated. In Scenario 3, essential oils are
removed from the solid waste through solvent-free microwave extraction, followed by anaerobic
digestion, while the wastewater is treated in a membrane bioreactor (MBR) and then in a UV
reactor.
The Life Cycle Assessment revealed significant differences in the environmental impacts of the
three alternative orange waste management scenarios. Specifically, Scenario 1, despite the high
energy demands of its processes, achieved a 36% reduction in climate change impact, owing to
the positive contribution of the produced biogas and fertilizer to the evaluated environmental
indicators. Scenario 2 exhibited the highest environmental burdens and was deemed
unsustainable, with notable increases in climate change and resource depletion impact
(exceeding 25% compared to the conventional method). In contrast, Scenario 3 demonstrated the
lowest environmental impact, achieving a 46% reduction in climate change and a 48% reduction
in resource depletion, confirming the effectiveness of using innovative and energy-efficient
technologies. In conclusion, the utilization of orange waste through approaches that include the
recovery of essential oils and the production of biofuels highlights environmental benefits, which,
combined with the economic benefits derived from the market disposal of the produced
products, make these methods particularly attractive for industrial-scale application. |
en |