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Crystallization of polyvinyl alcohol-water films by slow dehydration

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dc.contributor.author Peppas, NA en
dc.date.accessioned 2014-03-01T01:05:34Z
dc.date.available 2014-03-01T01:05:34Z
dc.date.issued 1976 en
dc.identifier.issn 0014-3057 en
dc.identifier.uri https://dspace.lib.ntua.gr/xmlui/handle/123456789/8884
dc.relation.uri http://www.scopus.com/inward/record.url?eid=2-s2.0-0005061518&partnerID=40&md5=69fde83f24564b9a09d9d7a359a633df en
dc.subject.classification Polymer Science en
dc.title Crystallization of polyvinyl alcohol-water films by slow dehydration en
heal.type journalArticle en
heal.language English en
heal.publicationDate 1976 en
heal.abstract Semicrystalline crosslinked poly(vinyl alcohol) hydrogels in the form of films were prepared by electron beam irradiation and a subsequent slow dehydration process at 25 ± 1°, using various drying agents. Nucleation and crystallization started after an induction time varying between 10 and 108 hr and proceeded very quickly, but always depending on the rate of evaporation of water. For the region of main growth of crystallites (degrees of crystallinity between 5 and 35%), the crystallization rate could be expressed by an Avrami equation; it was shown that the crystallization rate is lower for more densely crosslinked polymers under the same drying conditions. © 1976. en
heal.publisher PERGAMON-ELSEVIER SCIENCE LTD en
heal.journalName European Polymer Journal en
dc.identifier.isi ISI:A1976BY97000004 en
dc.identifier.volume 12 en
dc.identifier.issue 8 en
dc.identifier.spage 495 en
dc.identifier.epage 498 en


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