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Determination of absolute light-scattering cross sections of molten salts

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dc.contributor.author Raptis, C en
dc.date.accessioned 2014-03-01T01:06:34Z
dc.date.available 2014-03-01T01:06:34Z
dc.date.issued 1986 en
dc.identifier.issn 0021-8979 en
dc.identifier.uri https://dspace.lib.ntua.gr/xmlui/handle/123456789/9477
dc.subject.classification Physics, Applied en
dc.title Determination of absolute light-scattering cross sections of molten salts en
heal.type journalArticle en
heal.identifier.primary 10.1063/1.336478 en
heal.identifier.secondary http://dx.doi.org/10.1063/1.336478 en
heal.language English en
heal.publicationDate 1986 en
heal.abstract Systematic measurements have been made of absolute light-scattering cross sections of molten alkali halides by comparing in situ the scattering intensities of the melts to that of the 992-cm-1 line of benzene which has been used as intensity standard. All measurements have been made at about 30°above the melting point and from a low-frequency shift (ν̄) limit of 4 cm-1 to the highest possible, depending on the salt. The experimental method and comparison procedures (including data corrections) are described along with calculations of the solid angle of collection of the optical system. The resulting differential cross sections for polarized scattering vary between 2.3 × 10-29 (LiCl) and 1.2 × 10-28 cm2/ion pair sr (CsI), showing, in general, the anticipated trends with ion size and polarizability, that is, the larger the ion (the higher the polarizability), the more efficient the scatterer. en
heal.publisher AMER INST PHYSICS en
heal.journalName Journal of Applied Physics en
dc.identifier.doi 10.1063/1.336478 en
dc.identifier.isi ISI:A1986A716900040 en
dc.identifier.volume 59 en
dc.identifier.issue 5 en
dc.identifier.spage 1644 en
dc.identifier.epage 1652 en


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