dc.contributor.author |
Anagnostopoulou-Konsta, A |
en |
dc.contributor.author |
Pissis, P |
en |
dc.date.accessioned |
2014-03-01T01:06:44Z |
|
dc.date.available |
2014-03-01T01:06:44Z |
|
dc.date.issued |
1987 |
en |
dc.identifier.issn |
0022-3727 |
en |
dc.identifier.uri |
https://dspace.lib.ntua.gr/xmlui/handle/123456789/9595 |
|
dc.subject.classification |
Physics, Applied |
en |
dc.subject.other |
MOLECULES |
en |
dc.subject.other |
WATER - Dielectric Properties |
en |
dc.subject.other |
CASEIN HYDRATION |
en |
dc.subject.other |
DEPOLARIZATION CURRENTS |
en |
dc.subject.other |
BIOCHEMISTRY |
en |
dc.title |
A study of casein hydration by the thermally stimulated depolarisation currents method |
en |
heal.type |
journalArticle |
en |
heal.identifier.primary |
10.1088/0022-3727/20/9/013 |
en |
heal.identifier.secondary |
http://dx.doi.org/10.1088/0022-3727/20/9/013 |
en |
heal.identifier.secondary |
013 |
en |
heal.language |
English |
en |
heal.publicationDate |
1987 |
en |
heal.abstract |
The dielectric behaviour of bound water in compressed casein pellets has been studied using the thermally stimulated depolarisation currents method over the temperature range from 77 to 300 K and the hydration range from 1 to 24% w/w. Two distinct relaxation regions are obtained: one in the range of T from 100 to 170 K attributed to the reorientation of loosely bound water molecules, and a second one in the range 190-290 K interpreted mainly in terms of water-assisted relaxation of the protein polar groups. The fact that both relaxations are very markedly influenced by the presence of water for hydration contents, h, higher than 9%, strongly suggests that all water molecules sorbed up to this value are irrotationally bound to the protein macromolecules. Comparison with results obtained by other investigators by a variety of methods, as well as calculation of the primary sorption sites at the molecular level, give further support to the above interpretation. |
en |
heal.publisher |
IOP PUBLISHING LTD |
en |
heal.journalName |
Journal of Physics D: Applied Physics |
en |
dc.identifier.doi |
10.1088/0022-3727/20/9/013 |
en |
dc.identifier.isi |
ISI:A1987K065200013 |
en |
dc.identifier.volume |
20 |
en |
dc.identifier.issue |
9 |
en |
dc.identifier.spage |
1168 |
en |
dc.identifier.epage |
1174 |
en |