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PREDICTION OF VAPOR-LIQUID-EQUILIBRIUM WITH THE LCVM MODEL - A LINEAR COMBINATION OF THE VIDAL AND MICHELSEN MIXING RULES COUPLED WITH THE ORIGINAL UNIFAC AND THE T-MPR EQUATION OF STATE

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dc.contributor.author BOUKOUVALAS, C en
dc.contributor.author SPILIOTIS, N en
dc.contributor.author COUTSIKOS, P en
dc.contributor.author TZOUVARAS, N en
dc.contributor.author TASSIOS, D en
dc.date.accessioned 2014-03-01T11:45:34Z
dc.date.available 2014-03-01T11:45:34Z
dc.date.issued 1994 en
dc.identifier.issn 0378-3812 en
dc.identifier.uri https://dspace.lib.ntua.gr/xmlui/handle/123456789/37497
dc.subject THEORY en
dc.subject APPLICATION en
dc.subject EQUATION OF STATE en
dc.subject MIXING RULES en
dc.subject CUBIC en
dc.subject EMPIRICAL en
dc.subject EXCESS en
dc.subject FUNCTIONS en
dc.subject GROUP CONTRIBUTION en
dc.subject VAPOR-LIQUID EQUILIBRIA en
dc.subject INFINITE DILUTION ACTIVITY COEFFICIENTS en
dc.subject HYDROCARBONS en
dc.subject NON-HYDROCARBONS en
dc.subject POLAR en
dc.subject NONPOLAR en
dc.subject GASES en
dc.subject.classification Thermodynamics en
dc.subject.classification Chemistry, Physical en
dc.subject.classification Engineering, Chemical en
dc.subject.other PRESSURE PHASE-EQUILIBRIA en
dc.subject.other HEAVY NORMAL PARAFFINS en
dc.subject.other SYSTEM CARBON-DIOXIDE en
dc.subject.other NORMAL-HEXANE SYSTEM en
dc.subject.other GIBBS ENERGY MODELS en
dc.subject.other BINARY-MIXTURES en
dc.subject.other CUBIC EQUATIONS en
dc.subject.other N-DECANE en
dc.subject.other CONDENSATION BEHAVIOR en
dc.subject.other INTERFACIAL-TENSIONS en
dc.title PREDICTION OF VAPOR-LIQUID-EQUILIBRIUM WITH THE LCVM MODEL - A LINEAR COMBINATION OF THE VIDAL AND MICHELSEN MIXING RULES COUPLED WITH THE ORIGINAL UNIFAC AND THE T-MPR EQUATION OF STATE en
heal.type other en
heal.language English en
heal.publicationDate 1994 en
heal.abstract A new mixing rule, a linear combination of the Vidal and Michelsen rules, for the attractive term parameter in cubic equations of state (EoS) has been developed. This mixing rule, coupled with a translated and modified Peng-Robinson EoS and the original UNIFAC, leads to the LCVM model which provides successful prediction of vapor-liquid equilibria (VLE) of nonpolar and polar systems at low and high pressures. This also applies to systems of dissimilar component size, such as those containing gases (C2H6, CO2 and CH4) with large n-alkanes, where other EoS/G(E) predictive models, such as MHV2 and PSRK, perform poorly. en
heal.publisher ELSEVIER SCIENCE BV en
heal.journalName FLUID PHASE EQUILIBRIA en
dc.identifier.isi ISI:A1994MT13100005 en
dc.identifier.volume 92 en
dc.identifier.spage 75 en
dc.identifier.epage 106 en


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