GLC determination of silicon in alloys after chlorination with carbon tetrachloride

Parissakis, G; Iatridis, B

dc.contributor.author	Parissakis, G	en
dc.contributor.author	Iatridis, B	en
dc.date.accessioned	2014-03-01T01:05:38Z
dc.date.available	2014-03-01T01:05:38Z
dc.date.issued	1977	en
dc.identifier.issn	0009-5893	en
dc.identifier.uri	https://dspace.lib.ntua.gr/xmlui/handle/123456789/8908
dc.subject.classification	Biochemical Research Methods	en
dc.subject.classification	Chemistry, Analytical	en
dc.title	GLC determination of silicon in alloys after chlorination with carbon tetrachloride	en
heal.type	journalArticle	en
heal.identifier.primary	10.1007/BF02291588	en
heal.identifier.secondary	http://dx.doi.org/10.1007/BF02291588	en
heal.language	English	en
heal.publicationDate	1977	en
heal.abstract	By using carbon tetrachloride as chlorinating agent, the silicon contained in alloys can be quantitatively converted to silicon tetrachloride under certain conditions in a sealed glass tube (microreactor). This microreactor is then crushed by a special device which at the same time serves as an injection port to a gas chromatograph where the volatile products are separated and quantitatively determined. This method has been applied to a number of silicon alloys and is not time-consuming or costly, as many samples can be analysed in an hour with the use of common gas chromatographic systems. It is sensitive and selective, and it gives very accurate and precise (relative standard deviation <±0.5) results over a very wide range of silicon composition (∼1-99%). © 1977 Friedr. Vieweg & Sohn, Verlagsgesellschaft mbH.	en
heal.publisher	Springer-Verlag	en
heal.journalName	Chromatographia	en
dc.identifier.doi	10.1007/BF02291588	en
dc.identifier.isi	ISI:A1977CT46500008	en
dc.identifier.volume	10	en
dc.identifier.issue	1	en
dc.identifier.spage	37	en
dc.identifier.epage	39	en