Σύνθεση και χαρακτηρισμός παραγώγων του φουλερένιου

Abstract

The aim of this thesis was the synthesis and characterization of fullerene derivatives.More specifically has been the synthesis and characterization of two derivatives of fullerenes : C82H21N5O10 and C82H24N2O4 .Firstly held the preparation of a-amino acid which was used in subsequent cycloaddition reaction with the fullerene.Then after decarboxylation of alpha-amino acid is reacted with an aldehyde and fullerene in an organic solvent under heating (Prato’s reaction), resulting the synthesis of fouleropyrolidinis.Then took place the synthesis of 2-5-7- trinitrofluorenone-4-carboxylic acid, where this product is reacted with fouleropyrolidini and formed the derivative, C82H21N5O10. For the formation of the second derivative , C82H24N2O4, reaction took place between fouleropyrolidinis and flouorenonis-4-carboxylic acid. Then these two derivatives of fullerene characteristic withmass spectrometry and FT-IR spectomertry.